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CO2 electro-reduction CO2 hydrogenation CO2 methanation CO2 reduction H2 dropout Q1-390 QD1-999 QD450-801 Titania alkali oxide alkali promoter carbon dioxide carbon nanofibers carbon-based electrodes catalysis catalyst preparation dehydration diatomite dimethyl carbonate dynamic reaction conditions high pressure photocatalysis mechanochemistry metal-carbon-CNF composites microwaves n/a operando XAS photocatalysis photoreduction plastic waste quick-EXAFS