Research on Polyoxometalate Materials
Polyoxometalates (POMs) are a large and rapidly growing class of early-transition-metal oxide clusters. POMs are formed via acid-involved condensation reactions from monomeric oxometalate units, thus holding a special position (intermediate state) between monomeric oxometalate units and infinite met...
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| Idioma: | anglès |
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MDPI - Multidisciplinary Digital Publishing Institute
2023
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| Accés en línia: | ONIX_20231130_9783036593135_178 |
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| description | Polyoxometalates (POMs) are a large and rapidly growing class of early-transition-metal oxide clusters. POMs are formed via acid-involved condensation reactions from monomeric oxometalate units, thus holding a special position (intermediate state) between monomeric oxometalate units and infinite metal oxide frameworks. POMs continue to show remarkable advances and unexpected surprises in both their fundamentals and applications. The chemical compositions (addenda atoms) of POMs are mainly Mo, W, V, Nb, and Ta, and the heteroatoms of POMs are more variable, including P, As, B, Al, Si, Ge, S, and so on. The wide range of chemical composition variability and the large amount of unusual structural types enable POMs to exhibit a large number of different properties, such as rich solution equilibria, significant chemical and thermal stability, strong acidity, and the ability to act as proton–electron sinks due to their fast and reversible proton-coupled redox processes. Based on their intrinsic multifunctional nature, POMs have significant applications in catalysis, medicine, and materials science, etc. POMs not only can be used widely in different disciplines but can also be combined with polymers, oxides, ionic liquids, or carbonaceous supports to construct new and advanced composite (hybrid) materials, which have important, extensive applications in catalysis, electrode materials, electrocatalysis, photocatalysis, and so on. |
| format | Online |
| id | doab-20.500.12854ir-128726 |
| institution | Directory of Open Access Books |
| language | eng |
| publishDate | 2023 |
| publishDateRange | 2023 |
| publishDateSort | 2023 |
| publisher | MDPI - Multidisciplinary Digital Publishing Institute |
| publisherStr | MDPI - Multidisciplinary Digital Publishing Institute |
| record_format | ojs |
| spelling | doab-20.500.12854ir-1287262024-03-28T03:33:04Z Research on Polyoxometalate Materials Cui, Xiaobing vanadium-containing polyoxoniobates electrocatalysis benzyl alcohol oxidation nickel complexes polyoxometalate Anderson-Evans triol ligand cation-modulation polyoxometalates azobenzene photo-responsive ion-mobility mass spectrometry shape characterization TiO2 nanowire composite film bifunctional electrochromic energy storage hydrothermal syntheses cluster-organic frameworks helical chain vanadogermanate secondary transition metal substituted Ge-V-O clusters Anderson structure organic synthesis molecular catalysis green chemistry vanadomolybdate covalent modification hybrid decaborate DFT NMR hydrogen evolution reaction proton transfer octamolybdate chromatography structural analysis titanium zirconium transition metal substitution n/a thema EDItEUR::G Reference, Information and Interdisciplinary subjects::GP Research and information: general thema EDItEUR::P Mathematics and Science::PN Chemistry thema EDItEUR::P Mathematics and Science::PN Chemistry::PNK Inorganic chemistry Polyoxometalates (POMs) are a large and rapidly growing class of early-transition-metal oxide clusters. POMs are formed via acid-involved condensation reactions from monomeric oxometalate units, thus holding a special position (intermediate state) between monomeric oxometalate units and infinite metal oxide frameworks. POMs continue to show remarkable advances and unexpected surprises in both their fundamentals and applications. The chemical compositions (addenda atoms) of POMs are mainly Mo, W, V, Nb, and Ta, and the heteroatoms of POMs are more variable, including P, As, B, Al, Si, Ge, S, and so on. The wide range of chemical composition variability and the large amount of unusual structural types enable POMs to exhibit a large number of different properties, such as rich solution equilibria, significant chemical and thermal stability, strong acidity, and the ability to act as proton–electron sinks due to their fast and reversible proton-coupled redox processes. Based on their intrinsic multifunctional nature, POMs have significant applications in catalysis, medicine, and materials science, etc. POMs not only can be used widely in different disciplines but can also be combined with polymers, oxides, ionic liquids, or carbonaceous supports to construct new and advanced composite (hybrid) materials, which have important, extensive applications in catalysis, electrode materials, electrocatalysis, photocatalysis, and so on. 2023-11-30T20:46:58Z 2023-11-30T20:46:58Z 2023 book ONIX_20231130_9783036593135_178 9783036593135 9783036593128 https://directory.doabooks.org/handle/20.500.12854/128726 eng application/octet-stream Attribution 4.0 International https://mdpi.com/books/pdfview/book/8190 https://mdpi.com/books/pdfview/book/8190 MDPI - Multidisciplinary Digital Publishing Institute 10.3390/books978-3-0365-9312-8 10.3390/books978-3-0365-9312-8 46cabcaa-dd94-4bfe-87b4-55023c1b36d0 9783036593135 9783036593128 174 Basel open access |
| spellingShingle | vanadium-containing polyoxoniobates electrocatalysis benzyl alcohol oxidation nickel complexes polyoxometalate Anderson-Evans triol ligand cation-modulation polyoxometalates azobenzene photo-responsive ion-mobility mass spectrometry shape characterization TiO2 nanowire composite film bifunctional electrochromic energy storage hydrothermal syntheses cluster-organic frameworks helical chain vanadogermanate secondary transition metal substituted Ge-V-O clusters Anderson structure organic synthesis molecular catalysis green chemistry vanadomolybdate covalent modification hybrid decaborate DFT NMR hydrogen evolution reaction proton transfer octamolybdate chromatography structural analysis titanium zirconium transition metal substitution n/a thema EDItEUR::G Reference, Information and Interdisciplinary subjects::GP Research and information: general thema EDItEUR::P Mathematics and Science::PN Chemistry thema EDItEUR::P Mathematics and Science::PN Chemistry::PNK Inorganic chemistry Research on Polyoxometalate Materials |
| title | Research on Polyoxometalate Materials |
| title_full | Research on Polyoxometalate Materials |
| title_fullStr | Research on Polyoxometalate Materials |
| title_full_unstemmed | Research on Polyoxometalate Materials |
| title_short | Research on Polyoxometalate Materials |
| title_sort | research on polyoxometalate materials |
| topic | vanadium-containing polyoxoniobates electrocatalysis benzyl alcohol oxidation nickel complexes polyoxometalate Anderson-Evans triol ligand cation-modulation polyoxometalates azobenzene photo-responsive ion-mobility mass spectrometry shape characterization TiO2 nanowire composite film bifunctional electrochromic energy storage hydrothermal syntheses cluster-organic frameworks helical chain vanadogermanate secondary transition metal substituted Ge-V-O clusters Anderson structure organic synthesis molecular catalysis green chemistry vanadomolybdate covalent modification hybrid decaborate DFT NMR hydrogen evolution reaction proton transfer octamolybdate chromatography structural analysis titanium zirconium transition metal substitution n/a thema EDItEUR::G Reference, Information and Interdisciplinary subjects::GP Research and information: general thema EDItEUR::P Mathematics and Science::PN Chemistry thema EDItEUR::P Mathematics and Science::PN Chemistry::PNK Inorganic chemistry |
| topic_facet | vanadium-containing polyoxoniobates electrocatalysis benzyl alcohol oxidation nickel complexes polyoxometalate Anderson-Evans triol ligand cation-modulation polyoxometalates azobenzene photo-responsive ion-mobility mass spectrometry shape characterization TiO2 nanowire composite film bifunctional electrochromic energy storage hydrothermal syntheses cluster-organic frameworks helical chain vanadogermanate secondary transition metal substituted Ge-V-O clusters Anderson structure organic synthesis molecular catalysis green chemistry vanadomolybdate covalent modification hybrid decaborate DFT NMR hydrogen evolution reaction proton transfer octamolybdate chromatography structural analysis titanium zirconium transition metal substitution n/a thema EDItEUR::G Reference, Information and Interdisciplinary subjects::GP Research and information: general thema EDItEUR::P Mathematics and Science::PN Chemistry thema EDItEUR::P Mathematics and Science::PN Chemistry::PNK Inorganic chemistry |
| url | ONIX_20231130_9783036593135_178 |