Porphyrin-Based Compounds: Synthesis and Application
Porphyrins, metalloporphyrins, and their analogs are a family of macrocycles that are ubiquitous in nature, playing key roles in a myriad of biological functions, such as in plant light-harvesting (e.g., chlorophyll, a magnesium–chlorin complex), oxygen binding and transport (e.g., heme group, an ir...
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MDPI - Multidisciplinary Digital Publishing Institute
2023
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| Online adgang: | ONIX_20231130_9783036594002_272 |
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| description | Porphyrins, metalloporphyrins, and their analogs are a family of macrocycles that are ubiquitous in nature, playing key roles in a myriad of biological functions, such as in plant light-harvesting (e.g., chlorophyll, a magnesium–chlorin complex), oxygen binding and transport (e.g., heme group, an iron–porphyrin complex, responsible for animal cellular respiration), and bacteria photosynthesis. The pivotal functions fulfilled by these naturally occurring porphyrinoids have motivated and inspired organic chemists to produce synthetic porphyrins and analogs in the laboratory. In recent years, a multitude of applications for porphyrins has shifted the focus from purely academic interest to industrial processes. There is a growing recognition of the need to develop new, more selective, and environmentally friendly synthetic methods. Within this Special Issue, readers will find a collection of 16 original research papers and a comprehensive review, all dedicated to exploring the synthesis and functionalization of tetrapyrrolic macrocycles. These papers shed light on the vast potential applications of these compounds across various fields. |
| format | Online |
| id | doab-20.500.12854ir-128820 |
| institution | Directory of Open Access Books |
| language | eng |
| publishDate | 2023 |
| publishDateRange | 2023 |
| publishDateSort | 2023 |
| publisher | MDPI - Multidisciplinary Digital Publishing Institute |
| publisherStr | MDPI - Multidisciplinary Digital Publishing Institute |
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| spelling | doab-20.500.12854ir-1288202024-03-28T03:33:05Z Porphyrin-Based Compounds: Synthesis and Application Monteiro, Carlos J. P. Faustino, M. Amparo F. Serpa, Carlos porphyrin human serum albumin spectroscopy molecular docking chemical-biological interactions Spirulina maxima chlorophyll a derivatives photosensitizers semisynthesis photodynamic inactivation array artificial photosynthesis building block copper-free Sonogashira coupling ethyne perylene solar carboxylated pyrrolidine-fused chlorin fluorescence glutathione detection porphyrin macrocycles photodynamic therapy theranostic agents corroles trans-A2B-corroles photophysics photobiology asymmetrical porphyrins human U937 monocytic cells transmembrane potential membrane anisotropy sarco/endoplasmic reticulum Ca2+-ATPase (SERCA2b) Slo1 SUR2 asymmetric catalysis Diels–Alder reaction imidazolidin-4-ones organocatalysis photocatalysis porphyrins reductive amination sulfonamides MRSA antimicrobial resistance photosensitizer singlet oxygen potassium iodide gram-positive bacteria Staphylococcus aureus copper-64 positron emission tomography circular dichroism chirality chiral layers supramolecular chirality reflectance anisotropy spectroscopy DFT organometallic density functionals transition metals green chemistry C-H functionalization epoxidation iron porphyrin oxidation catalysis renewable aromatics phthalocyanines solubility gas sensors quartz microbalances porphyrinoids phenothiazine radical cation EPR spectroscopy ENDOR HYSCORE spectroelectrochemistry BODIPY pyridyl nitro chloro methyl ester n/a thema EDItEUR::G Reference, Information and Interdisciplinary subjects::GP Research and information: general thema EDItEUR::P Mathematics and Science::PN Chemistry thema EDItEUR::P Mathematics and Science::PN Chemistry::PNN Organic chemistry Porphyrins, metalloporphyrins, and their analogs are a family of macrocycles that are ubiquitous in nature, playing key roles in a myriad of biological functions, such as in plant light-harvesting (e.g., chlorophyll, a magnesium–chlorin complex), oxygen binding and transport (e.g., heme group, an iron–porphyrin complex, responsible for animal cellular respiration), and bacteria photosynthesis. The pivotal functions fulfilled by these naturally occurring porphyrinoids have motivated and inspired organic chemists to produce synthetic porphyrins and analogs in the laboratory. In recent years, a multitude of applications for porphyrins has shifted the focus from purely academic interest to industrial processes. There is a growing recognition of the need to develop new, more selective, and environmentally friendly synthetic methods. Within this Special Issue, readers will find a collection of 16 original research papers and a comprehensive review, all dedicated to exploring the synthesis and functionalization of tetrapyrrolic macrocycles. These papers shed light on the vast potential applications of these compounds across various fields. 2023-11-30T20:55:56Z 2023-11-30T20:55:56Z 2023 book ONIX_20231130_9783036594002_272 9783036594002 9783036594019 https://directory.doabooks.org/handle/20.500.12854/128820 eng application/octet-stream Attribution 4.0 International https://mdpi.com/books/pdfview/book/8288 https://mdpi.com/books/pdfview/book/8288 MDPI - Multidisciplinary Digital Publishing Institute 10.3390/books978-3-0365-9401-9 10.3390/books978-3-0365-9401-9 46cabcaa-dd94-4bfe-87b4-55023c1b36d0 9783036594002 9783036594019 298 Basel open access |
| spellingShingle | porphyrin human serum albumin spectroscopy molecular docking chemical-biological interactions Spirulina maxima chlorophyll a derivatives photosensitizers semisynthesis photodynamic inactivation array artificial photosynthesis building block copper-free Sonogashira coupling ethyne perylene solar carboxylated pyrrolidine-fused chlorin fluorescence glutathione detection porphyrin macrocycles photodynamic therapy theranostic agents corroles trans-A2B-corroles photophysics photobiology asymmetrical porphyrins human U937 monocytic cells transmembrane potential membrane anisotropy sarco/endoplasmic reticulum Ca2+-ATPase (SERCA2b) Slo1 SUR2 asymmetric catalysis Diels–Alder reaction imidazolidin-4-ones organocatalysis photocatalysis porphyrins reductive amination sulfonamides MRSA antimicrobial resistance photosensitizer singlet oxygen potassium iodide gram-positive bacteria Staphylococcus aureus copper-64 positron emission tomography circular dichroism chirality chiral layers supramolecular chirality reflectance anisotropy spectroscopy DFT organometallic density functionals transition metals green chemistry C-H functionalization epoxidation iron porphyrin oxidation catalysis renewable aromatics phthalocyanines solubility gas sensors quartz microbalances porphyrinoids phenothiazine radical cation EPR spectroscopy ENDOR HYSCORE spectroelectrochemistry BODIPY pyridyl nitro chloro methyl ester n/a thema EDItEUR::G Reference, Information and Interdisciplinary subjects::GP Research and information: general thema EDItEUR::P Mathematics and Science::PN Chemistry thema EDItEUR::P Mathematics and Science::PN Chemistry::PNN Organic chemistry Porphyrin-Based Compounds: Synthesis and Application |
| title | Porphyrin-Based Compounds: Synthesis and Application |
| title_full | Porphyrin-Based Compounds: Synthesis and Application |
| title_fullStr | Porphyrin-Based Compounds: Synthesis and Application |
| title_full_unstemmed | Porphyrin-Based Compounds: Synthesis and Application |
| title_short | Porphyrin-Based Compounds: Synthesis and Application |
| title_sort | porphyrin based compounds synthesis and application |
| topic | porphyrin human serum albumin spectroscopy molecular docking chemical-biological interactions Spirulina maxima chlorophyll a derivatives photosensitizers semisynthesis photodynamic inactivation array artificial photosynthesis building block copper-free Sonogashira coupling ethyne perylene solar carboxylated pyrrolidine-fused chlorin fluorescence glutathione detection porphyrin macrocycles photodynamic therapy theranostic agents corroles trans-A2B-corroles photophysics photobiology asymmetrical porphyrins human U937 monocytic cells transmembrane potential membrane anisotropy sarco/endoplasmic reticulum Ca2+-ATPase (SERCA2b) Slo1 SUR2 asymmetric catalysis Diels–Alder reaction imidazolidin-4-ones organocatalysis photocatalysis porphyrins reductive amination sulfonamides MRSA antimicrobial resistance photosensitizer singlet oxygen potassium iodide gram-positive bacteria Staphylococcus aureus copper-64 positron emission tomography circular dichroism chirality chiral layers supramolecular chirality reflectance anisotropy spectroscopy DFT organometallic density functionals transition metals green chemistry C-H functionalization epoxidation iron porphyrin oxidation catalysis renewable aromatics phthalocyanines solubility gas sensors quartz microbalances porphyrinoids phenothiazine radical cation EPR spectroscopy ENDOR HYSCORE spectroelectrochemistry BODIPY pyridyl nitro chloro methyl ester n/a thema EDItEUR::G Reference, Information and Interdisciplinary subjects::GP Research and information: general thema EDItEUR::P Mathematics and Science::PN Chemistry thema EDItEUR::P Mathematics and Science::PN Chemistry::PNN Organic chemistry |
| topic_facet | porphyrin human serum albumin spectroscopy molecular docking chemical-biological interactions Spirulina maxima chlorophyll a derivatives photosensitizers semisynthesis photodynamic inactivation array artificial photosynthesis building block copper-free Sonogashira coupling ethyne perylene solar carboxylated pyrrolidine-fused chlorin fluorescence glutathione detection porphyrin macrocycles photodynamic therapy theranostic agents corroles trans-A2B-corroles photophysics photobiology asymmetrical porphyrins human U937 monocytic cells transmembrane potential membrane anisotropy sarco/endoplasmic reticulum Ca2+-ATPase (SERCA2b) Slo1 SUR2 asymmetric catalysis Diels–Alder reaction imidazolidin-4-ones organocatalysis photocatalysis porphyrins reductive amination sulfonamides MRSA antimicrobial resistance photosensitizer singlet oxygen potassium iodide gram-positive bacteria Staphylococcus aureus copper-64 positron emission tomography circular dichroism chirality chiral layers supramolecular chirality reflectance anisotropy spectroscopy DFT organometallic density functionals transition metals green chemistry C-H functionalization epoxidation iron porphyrin oxidation catalysis renewable aromatics phthalocyanines solubility gas sensors quartz microbalances porphyrinoids phenothiazine radical cation EPR spectroscopy ENDOR HYSCORE spectroelectrochemistry BODIPY pyridyl nitro chloro methyl ester n/a thema EDItEUR::G Reference, Information and Interdisciplinary subjects::GP Research and information: general thema EDItEUR::P Mathematics and Science::PN Chemistry thema EDItEUR::P Mathematics and Science::PN Chemistry::PNN Organic chemistry |
| url | ONIX_20231130_9783036594002_272 |