Introducing the Effective Mass of Activated Complex and the Discussion on the Wave Function of this Instanton

Heterogeneous kinetics plays an important role in many scientific disciplines and industrial branches such as physical chemistry, materials science, chemical industry, ceramic industry, etc. Although many excellent books on theories and methods can be found, the aim of this book is to provide an unc...

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collection Directory of Open Access Books
description Heterogeneous kinetics plays an important role in many scientific disciplines and industrial branches such as physical chemistry, materials science, chemical industry, ceramic industry, etc. Although many excellent books on theories and methods can be found, the aim of this book is to provide an unconventional insight into the heterogeneous kinetics and properties of the activated complex. The introduction of the effective mass of this instanton enables to calculate many other properties, such as the most probable speed of activated complex, the momentum, the energetic density, the mass flux, etc., and to define two quantum numbers of activated state, i.e., the activation energy and the momentum. The monograph is organized into three chapters. The first of them deals with a short historical background, which introduces the beginning of chemical kinetics in the historical context. The second chapter is dedicated to the transition state theory, and the third one explains the concept of effective mass and effective rate of activated state as well as other properties of activated complex.
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spelling doab-20.500.12854ir-1302432024-04-05T12:31:10Z Introducing the Effective Mass of Activated Complex and the Discussion on the Wave Function of this Instanton Ptáček, Petr Opravil, Tomáš Šoukal, František kinetics, activation energy, schrödinger equation, arrhenius equation, momentum thema EDItEUR::P Mathematics and Science::PN Chemistry::PNR Physical chemistry Heterogeneous kinetics plays an important role in many scientific disciplines and industrial branches such as physical chemistry, materials science, chemical industry, ceramic industry, etc. Although many excellent books on theories and methods can be found, the aim of this book is to provide an unconventional insight into the heterogeneous kinetics and properties of the activated complex. The introduction of the effective mass of this instanton enables to calculate many other properties, such as the most probable speed of activated complex, the momentum, the energetic density, the mass flux, etc., and to define two quantum numbers of activated state, i.e., the activation energy and the momentum. The monograph is organized into three chapters. The first of them deals with a short historical background, which introduces the beginning of chemical kinetics in the historical context. The second chapter is dedicated to the transition state theory, and the third one explains the concept of effective mass and effective rate of activated state as well as other properties of activated complex. 2023-12-01T17:11:18Z 2023-12-01T17:11:18Z 2018 book ONIX_20231201_9781789234817_1352 9781789234817 9781789234800 9781838814755 https://directory.doabooks.org/handle/20.500.12854/130243 eng image/jpeg Attribution-NonCommercial 4.0 International https://www.intechopen.com/books/6445 https://mts.intechopen.com/storage/books/6445/authors_book/authors_book.pdf IntechOpen IntechOpen 10.5772/intechopen.70734 10.5772/intechopen.70734 78a36484-2c0c-47cb-ad67-2b9f5cd4a8f6 9781789234817 9781789234800 9781838814755 IntechOpen 104 open access
spellingShingle kinetics, activation energy, schrödinger equation, arrhenius equation, momentum
thema EDItEUR::P Mathematics and Science::PN Chemistry::PNR Physical chemistry
Introducing the Effective Mass of Activated Complex and the Discussion on the Wave Function of this Instanton
title Introducing the Effective Mass of Activated Complex and the Discussion on the Wave Function of this Instanton
title_full Introducing the Effective Mass of Activated Complex and the Discussion on the Wave Function of this Instanton
title_fullStr Introducing the Effective Mass of Activated Complex and the Discussion on the Wave Function of this Instanton
title_full_unstemmed Introducing the Effective Mass of Activated Complex and the Discussion on the Wave Function of this Instanton
title_short Introducing the Effective Mass of Activated Complex and the Discussion on the Wave Function of this Instanton
title_sort introducing the effective mass of activated complex and the discussion on the wave function of this instanton
topic kinetics, activation energy, schrödinger equation, arrhenius equation, momentum
thema EDItEUR::P Mathematics and Science::PN Chemistry::PNR Physical chemistry
topic_facet kinetics, activation energy, schrödinger equation, arrhenius equation, momentum
thema EDItEUR::P Mathematics and Science::PN Chemistry::PNR Physical chemistry
url ONIX_20231201_9781789234817_1352