The Polyhedral Face of Coordination Chemistry
This Special Issue intends to celebrate the multifaceted aspects of coordination chemistry by showcasing original work that demonstrates the liveliness and colourful nature of different branches of this discipline. The development of coordination chemistry as we know it owes much to crystallography,...
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| Formato: | Online |
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| Idioma: | inglês |
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MDPI - Multidisciplinary Digital Publishing Institute
2024
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| Acesso em linha: | ONIX_20240704_9783725812752_125 |
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| description | This Special Issue intends to celebrate the multifaceted aspects of coordination chemistry by showcasing original work that demonstrates the liveliness and colourful nature of different branches of this discipline. The development of coordination chemistry as we know it owes much to crystallography, with solid-state structural evidence playing a fundamental role in the definition and understanding of coordination compounds. Still, the very concept of coordination chemistry has expanded beyond the classical metal–ligand complexes: today, it encompasses supramolecular and bioinorganic compounds, metal–organic frameworks, and even organometallic species. The common thread to this apparently diverse range of topics lies in the “unique structural relationship”, as addressed by Donald Cram, that keeps a complex together, applying to both traditional coordination compounds as well as to host–guest systems. Solid state remains the chief technique for elucidating the interplay of interactions involved in a complex species and the precise spatial relationships among its constituents. Yet, the application of such knowledge and, thus, of broadly interpreted coordination chemistry, easily extends to catalysis, recognition and sensing in solution, metals in medicine, crystal engineering, material and reticular chemistry, and much more. |
| format | Online |
| id | doab-20.500.12854ir-139329 |
| institution | Directory of Open Access Books |
| language | eng |
| publishDate | 2024 |
| publishDateRange | 2024 |
| publishDateSort | 2024 |
| publisher | MDPI - Multidisciplinary Digital Publishing Institute |
| publisherStr | MDPI - Multidisciplinary Digital Publishing Institute |
| record_format | ojs |
| spelling | doab-20.500.12854ir-1393292024-07-04T09:42:54Z The Polyhedral Face of Coordination Chemistry Bianchi, Antonio Savastano, Matteo 2-hydroxypyridine hypercoordination 119Sn solid-state NMR tetrel X-ray diffraction lanthanide complexes crystal structure chemical speciation thiodiacetato complex 1,4,7-trithia-10-aza-cyclododecane macrocyclic ligands pendant arms conformation anion complexes perrhenate perchlorate anion–? cleft system heterometallic Cr-Cu complexes powder X-ray diffraction structural determination magnetism EPR spectroscopy single crystal lead complexes cobalt complexes heterometallic structures heptanuclear molecule transition metals metal ions coordination chemistry isostructural scorpiand-like ligands solvent extraction 2,2?-biimidazole crystal structures polynuclear complexes X-ray crystal structures Cu(II) 2-carboxyphenyliminodiacetic acid hydrazones Mo(VI) complexes structural analysis NMR spectroscopy cytotoxic and antibacterial activity thema EDItEUR::P Mathematics and Science thema EDItEUR::P Mathematics and Science::PN Chemistry thema EDItEUR::P Mathematics and Science::PN Chemistry::PNN Organic chemistry This Special Issue intends to celebrate the multifaceted aspects of coordination chemistry by showcasing original work that demonstrates the liveliness and colourful nature of different branches of this discipline. The development of coordination chemistry as we know it owes much to crystallography, with solid-state structural evidence playing a fundamental role in the definition and understanding of coordination compounds. Still, the very concept of coordination chemistry has expanded beyond the classical metal–ligand complexes: today, it encompasses supramolecular and bioinorganic compounds, metal–organic frameworks, and even organometallic species. The common thread to this apparently diverse range of topics lies in the “unique structural relationship”, as addressed by Donald Cram, that keeps a complex together, applying to both traditional coordination compounds as well as to host–guest systems. Solid state remains the chief technique for elucidating the interplay of interactions involved in a complex species and the precise spatial relationships among its constituents. Yet, the application of such knowledge and, thus, of broadly interpreted coordination chemistry, easily extends to catalysis, recognition and sensing in solution, metals in medicine, crystal engineering, material and reticular chemistry, and much more. 2024-07-04T09:42:51Z 2024-07-04T09:42:51Z 2024 book ONIX_20240704_9783725812752_125 9783725812752 9783725812769 https://directory.doabooks.org/handle/20.500.12854/139329 eng application/octet-stream Attribution-NonCommercial-NoDerivatives 4.0 International https://mdpi.com/books/pdfview/book/9326 https://mdpi.com/books/pdfview/book/9326 MDPI - Multidisciplinary Digital Publishing Institute 10.3390/books978-3-7258-1276-9 10.3390/books978-3-7258-1276-9 46cabcaa-dd94-4bfe-87b4-55023c1b36d0 9783725812752 9783725812769 142 open access |
| spellingShingle | 2-hydroxypyridine hypercoordination 119Sn solid-state NMR tetrel X-ray diffraction lanthanide complexes crystal structure chemical speciation thiodiacetato complex 1,4,7-trithia-10-aza-cyclododecane macrocyclic ligands pendant arms conformation anion complexes perrhenate perchlorate anion–? cleft system heterometallic Cr-Cu complexes powder X-ray diffraction structural determination magnetism EPR spectroscopy single crystal lead complexes cobalt complexes heterometallic structures heptanuclear molecule transition metals metal ions coordination chemistry isostructural scorpiand-like ligands solvent extraction 2,2?-biimidazole crystal structures polynuclear complexes X-ray crystal structures Cu(II) 2-carboxyphenyliminodiacetic acid hydrazones Mo(VI) complexes structural analysis NMR spectroscopy cytotoxic and antibacterial activity thema EDItEUR::P Mathematics and Science thema EDItEUR::P Mathematics and Science::PN Chemistry thema EDItEUR::P Mathematics and Science::PN Chemistry::PNN Organic chemistry The Polyhedral Face of Coordination Chemistry |
| title | The Polyhedral Face of Coordination Chemistry |
| title_full | The Polyhedral Face of Coordination Chemistry |
| title_fullStr | The Polyhedral Face of Coordination Chemistry |
| title_full_unstemmed | The Polyhedral Face of Coordination Chemistry |
| title_short | The Polyhedral Face of Coordination Chemistry |
| title_sort | polyhedral face of coordination chemistry |
| topic | 2-hydroxypyridine hypercoordination 119Sn solid-state NMR tetrel X-ray diffraction lanthanide complexes crystal structure chemical speciation thiodiacetato complex 1,4,7-trithia-10-aza-cyclododecane macrocyclic ligands pendant arms conformation anion complexes perrhenate perchlorate anion–? cleft system heterometallic Cr-Cu complexes powder X-ray diffraction structural determination magnetism EPR spectroscopy single crystal lead complexes cobalt complexes heterometallic structures heptanuclear molecule transition metals metal ions coordination chemistry isostructural scorpiand-like ligands solvent extraction 2,2?-biimidazole crystal structures polynuclear complexes X-ray crystal structures Cu(II) 2-carboxyphenyliminodiacetic acid hydrazones Mo(VI) complexes structural analysis NMR spectroscopy cytotoxic and antibacterial activity thema EDItEUR::P Mathematics and Science thema EDItEUR::P Mathematics and Science::PN Chemistry thema EDItEUR::P Mathematics and Science::PN Chemistry::PNN Organic chemistry |
| topic_facet | 2-hydroxypyridine hypercoordination 119Sn solid-state NMR tetrel X-ray diffraction lanthanide complexes crystal structure chemical speciation thiodiacetato complex 1,4,7-trithia-10-aza-cyclododecane macrocyclic ligands pendant arms conformation anion complexes perrhenate perchlorate anion–? cleft system heterometallic Cr-Cu complexes powder X-ray diffraction structural determination magnetism EPR spectroscopy single crystal lead complexes cobalt complexes heterometallic structures heptanuclear molecule transition metals metal ions coordination chemistry isostructural scorpiand-like ligands solvent extraction 2,2?-biimidazole crystal structures polynuclear complexes X-ray crystal structures Cu(II) 2-carboxyphenyliminodiacetic acid hydrazones Mo(VI) complexes structural analysis NMR spectroscopy cytotoxic and antibacterial activity thema EDItEUR::P Mathematics and Science thema EDItEUR::P Mathematics and Science::PN Chemistry thema EDItEUR::P Mathematics and Science::PN Chemistry::PNN Organic chemistry |
| url | ONIX_20240704_9783725812752_125 |