Photochemistry of Organic Molecules and of Matrix-Isolated Reactive Intermediates

This Special Issue of Molecules is dedicated to Prof. Rui Fausto in recognition of his influential contributions to the photochemistry of organic molecules and matrix-isolated reactive intermediates. Prof. Rui Fausto is one of the pioneers in applying vibrational excitation to induce chemical reacti...

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collection Directory of Open Access Books
description This Special Issue of Molecules is dedicated to Prof. Rui Fausto in recognition of his influential contributions to the photochemistry of organic molecules and matrix-isolated reactive intermediates. Prof. Rui Fausto is one of the pioneers in applying vibrational excitation to induce chemical reactivity in organic molecules under matrix isolation, and his research in infrared and ultraviolet-induced photochemistry has significantly advanced our understanding of organic compound reactivity. His more recent work on quantum mechanical tunneling has contributed significantly to the reflourishing of this field. Prof. Fausto is also a dedicated mentor, supporting and inspiring young scientists, and besides science, his interests include music and human rights advocacy; his intellectual and humanitarian outlooks enrich his legacy. This Special Issue comprises 12 articles that span a broad range of interests within the fields central to the scientific activity of Prof. Rui Fausto. We gratefully acknowledge the contributions of all colleagues and reviewers to this reprint celebrating Prof. Fausto's lasting impact.
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language eng
publishDate 2025
publishDateRange 2025
publishDateSort 2025
publisher MDPI - Multidisciplinary Digital Publishing Institute
publisherStr MDPI - Multidisciplinary Digital Publishing Institute
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spelling doab-20.500.12854ir-1529882025-02-20T13:23:25Z Photochemistry of Organic Molecules and of Matrix-Isolated Reactive Intermediates Ildiz, Gulce Ogruc Justino, Licinia L. G. diastereoselectivity photochemistry protecting groups diastereodifferentiating PABA PABA radical photolysis matrix isolation parahydrogen conformational switching near-IR laser irradiation intramolecular vibrational energy relaxation (IVR) quantum efficiency hydrogen atom tunneling 2-fluoro-4-hydroxy benzoic acid IR spectroscopy cyanine dyes DFT TDDFT UV-VIS spectroscopy fluorescence aggregation dimers DNA phosphorescence triplet state origin singlet-triplet energy gap vibrational frequencies porphyrin isomers Zn(II) complexes DFT calculations photocatalytic oxidation rate of recombination surface area 2-(2-nitrophenyl)-3H-indol-3-one thymol matrix-isolation IR spectra conformational isomerization H-tunneling acrylamide synchrotron radiation molecular modeling Raman spectroscopy human blood plasma BRCA mutation PLS-DA carbon disulfide chloromonofluoride Ga3+ alizarin sulfonate ARS NMR ATR-FTIR UV/vis fluorescent probe glycolic acid hydroxy acid dissociation isomerization chemical kinetics reaction mechanism vibrational spectroscopy thema EDItEUR::M Medicine and Nursing::MJ Clinical and internal medicine::MJC Diseases and disorders::MJCL Oncology thema EDItEUR::C Language and Linguistics::CJ Language teaching and learning thema EDItEUR::2 Language qualifiers::2A Indo-European languages::2AC Germanic and Scandinavian languages::2ACB English thema EDItEUR::4 Educational purpose qualifiers::4L For language learning courses and examinations::4LE For ELT / ESL learning, courses, examinations and certificates This Special Issue of Molecules is dedicated to Prof. Rui Fausto in recognition of his influential contributions to the photochemistry of organic molecules and matrix-isolated reactive intermediates. Prof. Rui Fausto is one of the pioneers in applying vibrational excitation to induce chemical reactivity in organic molecules under matrix isolation, and his research in infrared and ultraviolet-induced photochemistry has significantly advanced our understanding of organic compound reactivity. His more recent work on quantum mechanical tunneling has contributed significantly to the reflourishing of this field. Prof. Fausto is also a dedicated mentor, supporting and inspiring young scientists, and besides science, his interests include music and human rights advocacy; his intellectual and humanitarian outlooks enrich his legacy. This Special Issue comprises 12 articles that span a broad range of interests within the fields central to the scientific activity of Prof. Rui Fausto. We gratefully acknowledge the contributions of all colleagues and reviewers to this reprint celebrating Prof. Fausto's lasting impact. 2025-02-20T13:23:23Z 2025-02-20T13:23:23Z 2024 book ONIX_20250220_9783725826049_352 9783725826049 9783725826032 https://directory.doabooks.org/handle/20.500.12854/152988 eng application/octet-stream Attribution 4.0 International https://mdpi.com/books/pdfview/book/10248 MDPI - Multidisciplinary Digital Publishing Institute 10.3390/books978-3-7258-2603-2 10.3390/books978-3-7258-2603-2 46cabcaa-dd94-4bfe-87b4-55023c1b36d0 9783725826049 9783725826032 190 Basel open access
spellingShingle diastereoselectivity
photochemistry
protecting groups
diastereodifferentiating
PABA
PABA radical
photolysis
matrix isolation
parahydrogen
conformational switching
near-IR laser irradiation
intramolecular vibrational energy relaxation (IVR)
quantum efficiency
hydrogen atom tunneling
2-fluoro-4-hydroxy benzoic acid
IR spectroscopy
cyanine dyes
DFT
TDDFT
UV-VIS spectroscopy
fluorescence
aggregation
dimers
DNA
phosphorescence
triplet state origin
singlet-triplet energy gap
vibrational frequencies
porphyrin isomers
Zn(II) complexes
DFT calculations
photocatalytic oxidation
rate of recombination
surface area
2-(2-nitrophenyl)-3H-indol-3-one
thymol
matrix-isolation
IR spectra
conformational isomerization
H-tunneling
acrylamide
synchrotron radiation
molecular modeling
Raman spectroscopy
human blood plasma
BRCA mutation
PLS-DA
carbon disulfide
chloromonofluoride
Ga3+
alizarin sulfonate
ARS
NMR
ATR-FTIR
UV/vis
fluorescent probe
glycolic acid
hydroxy acid
dissociation
isomerization
chemical kinetics
reaction mechanism
vibrational spectroscopy
thema EDItEUR::M Medicine and Nursing::MJ Clinical and internal medicine::MJC Diseases and disorders::MJCL Oncology
thema EDItEUR::C Language and Linguistics::CJ Language teaching and learning
thema EDItEUR::2 Language qualifiers::2A Indo-European languages::2AC Germanic and Scandinavian languages::2ACB English
thema EDItEUR::4 Educational purpose qualifiers::4L For language learning courses and examinations::4LE For ELT / ESL learning, courses, examinations and certificates
Photochemistry of Organic Molecules and of Matrix-Isolated Reactive Intermediates
title Photochemistry of Organic Molecules and of Matrix-Isolated Reactive Intermediates
title_full Photochemistry of Organic Molecules and of Matrix-Isolated Reactive Intermediates
title_fullStr Photochemistry of Organic Molecules and of Matrix-Isolated Reactive Intermediates
title_full_unstemmed Photochemistry of Organic Molecules and of Matrix-Isolated Reactive Intermediates
title_short Photochemistry of Organic Molecules and of Matrix-Isolated Reactive Intermediates
title_sort photochemistry of organic molecules and of matrix isolated reactive intermediates
topic diastereoselectivity
photochemistry
protecting groups
diastereodifferentiating
PABA
PABA radical
photolysis
matrix isolation
parahydrogen
conformational switching
near-IR laser irradiation
intramolecular vibrational energy relaxation (IVR)
quantum efficiency
hydrogen atom tunneling
2-fluoro-4-hydroxy benzoic acid
IR spectroscopy
cyanine dyes
DFT
TDDFT
UV-VIS spectroscopy
fluorescence
aggregation
dimers
DNA
phosphorescence
triplet state origin
singlet-triplet energy gap
vibrational frequencies
porphyrin isomers
Zn(II) complexes
DFT calculations
photocatalytic oxidation
rate of recombination
surface area
2-(2-nitrophenyl)-3H-indol-3-one
thymol
matrix-isolation
IR spectra
conformational isomerization
H-tunneling
acrylamide
synchrotron radiation
molecular modeling
Raman spectroscopy
human blood plasma
BRCA mutation
PLS-DA
carbon disulfide
chloromonofluoride
Ga3+
alizarin sulfonate
ARS
NMR
ATR-FTIR
UV/vis
fluorescent probe
glycolic acid
hydroxy acid
dissociation
isomerization
chemical kinetics
reaction mechanism
vibrational spectroscopy
thema EDItEUR::M Medicine and Nursing::MJ Clinical and internal medicine::MJC Diseases and disorders::MJCL Oncology
thema EDItEUR::C Language and Linguistics::CJ Language teaching and learning
thema EDItEUR::2 Language qualifiers::2A Indo-European languages::2AC Germanic and Scandinavian languages::2ACB English
thema EDItEUR::4 Educational purpose qualifiers::4L For language learning courses and examinations::4LE For ELT / ESL learning, courses, examinations and certificates
topic_facet diastereoselectivity
photochemistry
protecting groups
diastereodifferentiating
PABA
PABA radical
photolysis
matrix isolation
parahydrogen
conformational switching
near-IR laser irradiation
intramolecular vibrational energy relaxation (IVR)
quantum efficiency
hydrogen atom tunneling
2-fluoro-4-hydroxy benzoic acid
IR spectroscopy
cyanine dyes
DFT
TDDFT
UV-VIS spectroscopy
fluorescence
aggregation
dimers
DNA
phosphorescence
triplet state origin
singlet-triplet energy gap
vibrational frequencies
porphyrin isomers
Zn(II) complexes
DFT calculations
photocatalytic oxidation
rate of recombination
surface area
2-(2-nitrophenyl)-3H-indol-3-one
thymol
matrix-isolation
IR spectra
conformational isomerization
H-tunneling
acrylamide
synchrotron radiation
molecular modeling
Raman spectroscopy
human blood plasma
BRCA mutation
PLS-DA
carbon disulfide
chloromonofluoride
Ga3+
alizarin sulfonate
ARS
NMR
ATR-FTIR
UV/vis
fluorescent probe
glycolic acid
hydroxy acid
dissociation
isomerization
chemical kinetics
reaction mechanism
vibrational spectroscopy
thema EDItEUR::M Medicine and Nursing::MJ Clinical and internal medicine::MJC Diseases and disorders::MJCL Oncology
thema EDItEUR::C Language and Linguistics::CJ Language teaching and learning
thema EDItEUR::2 Language qualifiers::2A Indo-European languages::2AC Germanic and Scandinavian languages::2ACB English
thema EDItEUR::4 Educational purpose qualifiers::4L For language learning courses and examinations::4LE For ELT / ESL learning, courses, examinations and certificates
url ONIX_20250220_9783725826049_352