Catalysis by Precious Metals, Past and Future
The future of the precious metals is shiny and resistant. Although expensive and potentially replaceable by transition metal catalysts, precious metal implementation in research and industry shows potential. These metals catalyze oxidation and hydrogenation due to their dissociative behavior toward...
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| Автори: | , |
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| Формат: | Online |
| Мова: | Англійська |
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MDPI - Multidisciplinary Digital Publishing Institute
2021
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| Онлайн доступ: | 46001 |
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| _version_ | 1869522221486047232 |
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| author | Tejada, Marcela Martinez Ivanova, Svetlana |
| author_browse | Ivanova, Svetlana Tejada, Marcela Martinez |
| author_facet | Tejada, Marcela Martinez Ivanova, Svetlana |
| author_sort | Tejada, Marcela Martinez |
| collection | Directory of Open Access Books |
| description | The future of the precious metals is shiny and resistant. Although expensive and potentially replaceable by transition metal catalysts, precious metal implementation in research and industry shows potential. These metals catalyze oxidation and hydrogenation due to their dissociative behavior toward hydrogen and oxygen, dehydrogenation, isomerization, and aromatization, etc. The precious metal catalysts, especially platinum-based catalysts, are involved in a variety of industrial processes. Examples include Pt–Rh gauze for nitric acid production, the Pt/Al2O3 catalyst for cyclohexane and propylene production, and Pd/Al2O3 catalysts for petrochemical hydropurification reactions, etc. A quick search of the number of published articles in the last five years containing a combination of corresponding “metals” (Pt, Pd, Ru, Rh and Au) and “catalysts” as keywords indicates the importance of the Pt catalysts, but also the continuous increase in the contribution of Pd and Au. This Special Issue reveals the importance of precious metals in catalysis and focuses on mono- and bi-metallic formulations of any supported precious metals and their promotional catalytic effect of other transition metals. The application of precious metals in diverse reactions, either homogeneous or heterogeneous, and studies of the preparation, characterization, and applications of the supported precious metal catalysts, are presented. |
| format | Online |
| id | doab-20.500.12854ir-42787 |
| institution | Directory of Open Access Books |
| language | eng |
| publishDate | 2021 |
| publishDateRange | 2021 |
| publishDateSort | 2021 |
| publisher | MDPI - Multidisciplinary Digital Publishing Institute |
| publisherStr | MDPI - Multidisciplinary Digital Publishing Institute |
| record_format | ojs |
| spelling | doab-20.500.12854ir-427872024-04-05T12:39:21Z Catalysis by Precious Metals, Past and Future Tejada, Marcela Martinez Ivanova, Svetlana QD1-999 QD146-197 Q1-390 sustainable ammonia synthesis Pt3Sn alloy alkenols n/a PtSn alloy propane dehydrogenation chelate photodegradation gold nanoparticles photochemical alkynols triple bond electron charge palladium catalyst Pt/Al2O3 2-methyl-3-butyn-2-ol hydrogen storage X-ray crystallography ruthenium platinum dispersion gold catalysts reduction temperature DOC palladium renewable hydrogen 1-propanol 4-hydroxyproline glycerol 2-?-benzylproline proline hydrogen bonding oxidative coupling glucose oxidation stabilizing agent titania 4-fluoroproline turnover frequency porous carbons Pt–Sn/Al2O3 P25@Pd catalyst synthesis 2-propanol amino acid azetidine precious metals clay gas phase hydrogenation CNTs 3-butyn-2-ol Pd/Al2O3 heterogeneous enantioselective hydrogenation XPS microwave caesium perovskite CO oxidation Au–TiO2 dodecahydro-N-ethylcarbazole phenol photo-degradation pipecolinic acid 3-butyn-1-ol acetophenone drying palladium catalysts N-methylproline dehydrogenation PVA aging hydrodechlorination hydrogenolysis dispersion direct reduction core-shell thema EDItEUR::P Mathematics and Science::PN Chemistry The future of the precious metals is shiny and resistant. Although expensive and potentially replaceable by transition metal catalysts, precious metal implementation in research and industry shows potential. These metals catalyze oxidation and hydrogenation due to their dissociative behavior toward hydrogen and oxygen, dehydrogenation, isomerization, and aromatization, etc. The precious metal catalysts, especially platinum-based catalysts, are involved in a variety of industrial processes. Examples include Pt–Rh gauze for nitric acid production, the Pt/Al2O3 catalyst for cyclohexane and propylene production, and Pd/Al2O3 catalysts for petrochemical hydropurification reactions, etc. A quick search of the number of published articles in the last five years containing a combination of corresponding “metals” (Pt, Pd, Ru, Rh and Au) and “catalysts” as keywords indicates the importance of the Pt catalysts, but also the continuous increase in the contribution of Pd and Au. This Special Issue reveals the importance of precious metals in catalysis and focuses on mono- and bi-metallic formulations of any supported precious metals and their promotional catalytic effect of other transition metals. The application of precious metals in diverse reactions, either homogeneous or heterogeneous, and studies of the preparation, characterization, and applications of the supported precious metal catalysts, are presented. 2021-02-11T09:34:37Z 2021-02-11T09:34:37Z 2020-06-09 16:38:57 2020 book 46001 9783039287239 9783039287222 https://directory.doabooks.org/handle/20.500.12854/42787 eng application/octet-stream Attribution-NonCommercial-NoDerivatives 4.0 International https://mdpi.com/books/pdfview/book/2176 MDPI - Multidisciplinary Digital Publishing Institute 10.3390/books978-3-03928-723-9 10.3390/books978-3-03928-723-9 46cabcaa-dd94-4bfe-87b4-55023c1b36d0 9783039287239 9783039287222 204 open access |
| spellingShingle | QD1-999 QD146-197 Q1-390 sustainable ammonia synthesis Pt3Sn alloy alkenols n/a PtSn alloy propane dehydrogenation chelate photodegradation gold nanoparticles photochemical alkynols triple bond electron charge palladium catalyst Pt/Al2O3 2-methyl-3-butyn-2-ol hydrogen storage X-ray crystallography ruthenium platinum dispersion gold catalysts reduction temperature DOC palladium renewable hydrogen 1-propanol 4-hydroxyproline glycerol 2-?-benzylproline proline hydrogen bonding oxidative coupling glucose oxidation stabilizing agent titania 4-fluoroproline turnover frequency porous carbons Pt–Sn/Al2O3 P25@Pd catalyst synthesis 2-propanol amino acid azetidine precious metals clay gas phase hydrogenation CNTs 3-butyn-2-ol Pd/Al2O3 heterogeneous enantioselective hydrogenation XPS microwave caesium perovskite CO oxidation Au–TiO2 dodecahydro-N-ethylcarbazole phenol photo-degradation pipecolinic acid 3-butyn-1-ol acetophenone drying palladium catalysts N-methylproline dehydrogenation PVA aging hydrodechlorination hydrogenolysis dispersion direct reduction core-shell thema EDItEUR::P Mathematics and Science::PN Chemistry Tejada, Marcela Martinez Ivanova, Svetlana Catalysis by Precious Metals, Past and Future |
| title | Catalysis by Precious Metals, Past and Future |
| title_full | Catalysis by Precious Metals, Past and Future |
| title_fullStr | Catalysis by Precious Metals, Past and Future |
| title_full_unstemmed | Catalysis by Precious Metals, Past and Future |
| title_short | Catalysis by Precious Metals, Past and Future |
| title_sort | catalysis by precious metals past and future |
| topic | QD1-999 QD146-197 Q1-390 sustainable ammonia synthesis Pt3Sn alloy alkenols n/a PtSn alloy propane dehydrogenation chelate photodegradation gold nanoparticles photochemical alkynols triple bond electron charge palladium catalyst Pt/Al2O3 2-methyl-3-butyn-2-ol hydrogen storage X-ray crystallography ruthenium platinum dispersion gold catalysts reduction temperature DOC palladium renewable hydrogen 1-propanol 4-hydroxyproline glycerol 2-?-benzylproline proline hydrogen bonding oxidative coupling glucose oxidation stabilizing agent titania 4-fluoroproline turnover frequency porous carbons Pt–Sn/Al2O3 P25@Pd catalyst synthesis 2-propanol amino acid azetidine precious metals clay gas phase hydrogenation CNTs 3-butyn-2-ol Pd/Al2O3 heterogeneous enantioselective hydrogenation XPS microwave caesium perovskite CO oxidation Au–TiO2 dodecahydro-N-ethylcarbazole phenol photo-degradation pipecolinic acid 3-butyn-1-ol acetophenone drying palladium catalysts N-methylproline dehydrogenation PVA aging hydrodechlorination hydrogenolysis dispersion direct reduction core-shell thema EDItEUR::P Mathematics and Science::PN Chemistry |
| topic_facet | QD1-999 QD146-197 Q1-390 sustainable ammonia synthesis Pt3Sn alloy alkenols n/a PtSn alloy propane dehydrogenation chelate photodegradation gold nanoparticles photochemical alkynols triple bond electron charge palladium catalyst Pt/Al2O3 2-methyl-3-butyn-2-ol hydrogen storage X-ray crystallography ruthenium platinum dispersion gold catalysts reduction temperature DOC palladium renewable hydrogen 1-propanol 4-hydroxyproline glycerol 2-?-benzylproline proline hydrogen bonding oxidative coupling glucose oxidation stabilizing agent titania 4-fluoroproline turnover frequency porous carbons Pt–Sn/Al2O3 P25@Pd catalyst synthesis 2-propanol amino acid azetidine precious metals clay gas phase hydrogenation CNTs 3-butyn-2-ol Pd/Al2O3 heterogeneous enantioselective hydrogenation XPS microwave caesium perovskite CO oxidation Au–TiO2 dodecahydro-N-ethylcarbazole phenol photo-degradation pipecolinic acid 3-butyn-1-ol acetophenone drying palladium catalysts N-methylproline dehydrogenation PVA aging hydrodechlorination hydrogenolysis dispersion direct reduction core-shell thema EDItEUR::P Mathematics and Science::PN Chemistry |
| url | 46001 |
| work_keys_str_mv | AT tejadamarcelamartinez catalysisbypreciousmetalspastandfuture AT ivanovasvetlana catalysisbypreciousmetalspastandfuture |