On the diverse bonding situations in nanostructures : an ab initio computational study

This computational study investigates diverse bonding situations in nanostructures (carbon nanotubes, fullerenes, metal compounds) spanning a broad range of energies. Weak, dispersive interactions and covalent metal-ligand and metal-metal bonding are examined. The results of efficient density functi...

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Hlavní autor: Pankewitz, Tobias
Médium: Online
Jazyk:angličtina
Vydáno: KIT Scientific Publishing 2021
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On-line přístup:34552
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Popis
Shrnutí:This computational study investigates diverse bonding situations in nanostructures (carbon nanotubes, fullerenes, metal compounds) spanning a broad range of energies. Weak, dispersive interactions and covalent metal-ligand and metal-metal bonding are examined. The results of efficient density functional calculations are compared to those of correlated wavefunction calculations on model systems. This rigorous validation is crucial in evaluating the balance between computational cost and accuracy.