POSS-Based Polymers

The combination of functional polymers with inorganic nanostructured compounds has become a major area of research and technological development owing to the remarkable properties and multifunctionalities deriving from their nano and hybrid structures. In this context, polyhedral oligomeric silsesqu...

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Главный автор: Blanco, Ignazio
Формат: Online
Язык:английский
Опубликовано: MDPI - Multidisciplinary Digital Publishing Institute 2021
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Online-ссылка:43237
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author Blanco, Ignazio
author_browse Blanco, Ignazio
author_facet Blanco, Ignazio
author_sort Blanco, Ignazio
collection Directory of Open Access Books
description The combination of functional polymers with inorganic nanostructured compounds has become a major area of research and technological development owing to the remarkable properties and multifunctionalities deriving from their nano and hybrid structures. In this context, polyhedral oligomeric silsesquioxanes (POSSs) have increasing importance and a dominant position with respect to the reinforcement of polymeric materials. Although POSSs were first described in 1946 by Scott, these materials, however, have not immediately been successful if we consider that, starting from 1946 and up to 1995, we find in the literature 85 manuscripts regarding POSSs; which means that less than two papers per year were published over 50 years. Since 1995, we observe an exponential growth of scientific manuscripts concerning POSSs. It is changing from an annual average of 20 manuscripts for the period 1995–2000 to an annual average of about 400 manuscripts, with an increase of 2800%. The introduction of POSSs inorganic nanostructures into polymers gives rise to polymer nanostructured materials (PNMs) with interesting mechanical and physical properties, thus representing a radical alternative to the traditional filled polymers or polymer compositions.
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publishDate 2021
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publisherStr MDPI - Multidisciplinary Digital Publishing Institute
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spelling doab-20.500.12854ir-567022024-04-11T15:11:34Z POSS-Based Polymers Blanco, Ignazio TA1-2040 T1-995 graphene oxide n/a lithium ion battery liquefied polypropylene silsesquioxanes self-assembly behaviors nanocomposites Octavinyl-POSS polyimide thermal properties polyhedral oligomeric silsesquioxane-based ionic liquids aqueous self-assembly bi-functional POSS blends low refractive material cellular structure mechanism analysis morphology flame retardant hydrogels mercapto-modified damping POSS nanoparticles phthalonitrile polymers mechanical properties flame-retardant mechanism thiol-ene ‘click’ reaction POSS poly(?-caprolactone) siloxane-silsesquioxane resins polyhedral oligomeric silsesquioxane (POSS) surface properties fluoropolymer thiol–ene “click” reaction Monomethacryloxy POSS monodisperse thermogravimetry OLEDs fluorescent sensors double-decker-shaped silsesquioxane (DDSQ) dielectric constant composites organic-inorganic hybrids poly(?-caprolactone) nanocomposite POSS-based copolymer organic-inorganic crosslinking optoelectronics flame retardancy cone calorimeter tests lauryl methacrylate octa-ammonium POSS nitroaromatic explosives phthalonitrile-polyhedral oligomeric silsesquioxane copolymers cyanate ester thermoplastic polyurethane sodium alginate giant surfactant benzoxazine thermal stability temperature responsiveness polymerization kinetics mechanical performance Si@C anode ridgid polyurethane foams epoxy resin grafting synthesis direct synthesis filler bridged silsesquioxane hydrophobic modification dispersion polyhedral oligomeric silsesquioxanes anchor effect thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TB Technology: general issues::TBX History of engineering and technology The combination of functional polymers with inorganic nanostructured compounds has become a major area of research and technological development owing to the remarkable properties and multifunctionalities deriving from their nano and hybrid structures. In this context, polyhedral oligomeric silsesquioxanes (POSSs) have increasing importance and a dominant position with respect to the reinforcement of polymeric materials. Although POSSs were first described in 1946 by Scott, these materials, however, have not immediately been successful if we consider that, starting from 1946 and up to 1995, we find in the literature 85 manuscripts regarding POSSs; which means that less than two papers per year were published over 50 years. Since 1995, we observe an exponential growth of scientific manuscripts concerning POSSs. It is changing from an annual average of 20 manuscripts for the period 1995–2000 to an annual average of about 400 manuscripts, with an increase of 2800%. The introduction of POSSs inorganic nanostructures into polymers gives rise to polymer nanostructured materials (PNMs) with interesting mechanical and physical properties, thus representing a radical alternative to the traditional filled polymers or polymer compositions. 2021-02-11T23:32:03Z 2021-02-11T23:32:03Z 2020-01-07 09:08:26 2019 book 43237 9783039219940 9783039219957 https://directory.doabooks.org/handle/20.500.12854/56702 eng application/octet-stream Attribution-NonCommercial-NoDerivatives 4.0 International https://mdpi.com/books/pdfview/book/1907 MDPI - Multidisciplinary Digital Publishing Institute 10.3390/books978-3-03921-995-7 10.3390/books978-3-03921-995-7 46cabcaa-dd94-4bfe-87b4-55023c1b36d0 9783039219940 9783039219957 310 open access
spellingShingle TA1-2040
T1-995
graphene oxide
n/a
lithium ion battery
liquefied
polypropylene
silsesquioxanes
self-assembly behaviors
nanocomposites
Octavinyl-POSS
polyimide
thermal properties
polyhedral oligomeric silsesquioxane-based ionic liquids
aqueous self-assembly
bi-functional POSS
blends
low refractive material
cellular structure
mechanism analysis
morphology
flame retardant
hydrogels
mercapto-modified
damping
POSS nanoparticles
phthalonitrile polymers
mechanical properties
flame-retardant mechanism
thiol-ene ‘click’ reaction
POSS
poly(?-caprolactone)
siloxane-silsesquioxane resins
polyhedral oligomeric silsesquioxane (POSS)
surface properties
fluoropolymer
thiol–ene “click” reaction
Monomethacryloxy POSS
monodisperse
thermogravimetry
OLEDs
fluorescent sensors
double-decker-shaped silsesquioxane (DDSQ)
dielectric constant
composites
organic-inorganic hybrids
poly(?-caprolactone) nanocomposite
POSS-based copolymer
organic-inorganic crosslinking
optoelectronics
flame retardancy
cone calorimeter tests
lauryl methacrylate
octa-ammonium POSS
nitroaromatic explosives
phthalonitrile-polyhedral oligomeric silsesquioxane copolymers
cyanate ester
thermoplastic polyurethane
sodium alginate
giant surfactant
benzoxazine
thermal stability
temperature responsiveness
polymerization kinetics
mechanical performance
Si@C anode
ridgid polyurethane foams
epoxy resin
grafting synthesis
direct synthesis
filler
bridged silsesquioxane
hydrophobic modification
dispersion
polyhedral oligomeric silsesquioxanes
anchor effect
thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TB Technology: general issues::TBX History of engineering and technology
Blanco, Ignazio
POSS-Based Polymers
title POSS-Based Polymers
title_full POSS-Based Polymers
title_fullStr POSS-Based Polymers
title_full_unstemmed POSS-Based Polymers
title_short POSS-Based Polymers
title_sort poss based polymers
topic TA1-2040
T1-995
graphene oxide
n/a
lithium ion battery
liquefied
polypropylene
silsesquioxanes
self-assembly behaviors
nanocomposites
Octavinyl-POSS
polyimide
thermal properties
polyhedral oligomeric silsesquioxane-based ionic liquids
aqueous self-assembly
bi-functional POSS
blends
low refractive material
cellular structure
mechanism analysis
morphology
flame retardant
hydrogels
mercapto-modified
damping
POSS nanoparticles
phthalonitrile polymers
mechanical properties
flame-retardant mechanism
thiol-ene ‘click’ reaction
POSS
poly(?-caprolactone)
siloxane-silsesquioxane resins
polyhedral oligomeric silsesquioxane (POSS)
surface properties
fluoropolymer
thiol–ene “click” reaction
Monomethacryloxy POSS
monodisperse
thermogravimetry
OLEDs
fluorescent sensors
double-decker-shaped silsesquioxane (DDSQ)
dielectric constant
composites
organic-inorganic hybrids
poly(?-caprolactone) nanocomposite
POSS-based copolymer
organic-inorganic crosslinking
optoelectronics
flame retardancy
cone calorimeter tests
lauryl methacrylate
octa-ammonium POSS
nitroaromatic explosives
phthalonitrile-polyhedral oligomeric silsesquioxane copolymers
cyanate ester
thermoplastic polyurethane
sodium alginate
giant surfactant
benzoxazine
thermal stability
temperature responsiveness
polymerization kinetics
mechanical performance
Si@C anode
ridgid polyurethane foams
epoxy resin
grafting synthesis
direct synthesis
filler
bridged silsesquioxane
hydrophobic modification
dispersion
polyhedral oligomeric silsesquioxanes
anchor effect
thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TB Technology: general issues::TBX History of engineering and technology
topic_facet TA1-2040
T1-995
graphene oxide
n/a
lithium ion battery
liquefied
polypropylene
silsesquioxanes
self-assembly behaviors
nanocomposites
Octavinyl-POSS
polyimide
thermal properties
polyhedral oligomeric silsesquioxane-based ionic liquids
aqueous self-assembly
bi-functional POSS
blends
low refractive material
cellular structure
mechanism analysis
morphology
flame retardant
hydrogels
mercapto-modified
damping
POSS nanoparticles
phthalonitrile polymers
mechanical properties
flame-retardant mechanism
thiol-ene ‘click’ reaction
POSS
poly(?-caprolactone)
siloxane-silsesquioxane resins
polyhedral oligomeric silsesquioxane (POSS)
surface properties
fluoropolymer
thiol–ene “click” reaction
Monomethacryloxy POSS
monodisperse
thermogravimetry
OLEDs
fluorescent sensors
double-decker-shaped silsesquioxane (DDSQ)
dielectric constant
composites
organic-inorganic hybrids
poly(?-caprolactone) nanocomposite
POSS-based copolymer
organic-inorganic crosslinking
optoelectronics
flame retardancy
cone calorimeter tests
lauryl methacrylate
octa-ammonium POSS
nitroaromatic explosives
phthalonitrile-polyhedral oligomeric silsesquioxane copolymers
cyanate ester
thermoplastic polyurethane
sodium alginate
giant surfactant
benzoxazine
thermal stability
temperature responsiveness
polymerization kinetics
mechanical performance
Si@C anode
ridgid polyurethane foams
epoxy resin
grafting synthesis
direct synthesis
filler
bridged silsesquioxane
hydrophobic modification
dispersion
polyhedral oligomeric silsesquioxanes
anchor effect
thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TB Technology: general issues::TBX History of engineering and technology
url 43237
work_keys_str_mv AT blancoignazio possbasedpolymers