s-Block Metal Complexes
The coordination chemistry of the s-block metals spans diverse fields, ranging from shielded coordination compounds over hydride to organometallic complexes for diverse applications. New developments pertain, not only to the lithium and magnesium chemistry with inspiring examples, such as heterobime...
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| 第一著者: | |
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| フォーマット: | Online |
| 言語: | 英語 |
| 出版事項: |
MDPI - Multidisciplinary Digital Publishing Institute
2021
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| 主題: | |
| オンライン･アクセス: | 24752 |
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| _version_ | 1869529561040945152 |
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| author | Matthias Westerhausen (Ed.) |
| author_browse | Matthias Westerhausen (Ed.) |
| author_facet | Matthias Westerhausen (Ed.) |
| author_sort | Matthias Westerhausen (Ed.) |
| collection | Directory of Open Access Books |
| description | The coordination chemistry of the s-block metals spans diverse fields, ranging from shielded coordination compounds over hydride to organometallic complexes for diverse applications. New developments pertain, not only to the lithium and magnesium chemistry with inspiring examples, such as heterobimetallic or heteroleptic complexes with special reactivity patterns, but the heavy s-block metals have progressively gained attention in various fields. Subvalent magnesium(I) derivatives are increasingly being used for reduction reactions, turbo-Grignard reagents show enhanced reactivity and tolerance toward functional groups, hydrides act as hydrogen storage materials, heavy Grignard reagents are available by straight forward procedures—just to name a few examples. Quantum chemical calculations deal with unique bonding situations and the relevance of d-orbital participation has been discussed to understand structure-reactivity relationships. Especially the complexes of the heavy alkaline earth metals are catalytically active in diverse reactions, promoting hydrofunctionalization reactions and Lewis acid catalysis. This Special Issue aims to highlight the structural and chemical diversity of s-block metal complexes, as well as the broad field of applications. |
| format | Online |
| id | doab-20.500.12854ir-58746 |
| institution | Directory of Open Access Books |
| language | eng |
| publishDate | 2021 |
| publishDateRange | 2021 |
| publishDateSort | 2021 |
| publisher | MDPI - Multidisciplinary Digital Publishing Institute |
| publisherStr | MDPI - Multidisciplinary Digital Publishing Institute |
| record_format | ojs |
| spelling | doab-20.500.12854ir-587462024-04-05T12:39:49Z s-Block Metal Complexes Matthias Westerhausen (Ed.) QD1-999 s-block metal coordination compounds Grignard-type reagents Lochmann-Schlosser bases heterobimetallic complexes s-block metal-mediated catalysis bonding in s-block complexes thema EDItEUR::P Mathematics and Science::PN Chemistry The coordination chemistry of the s-block metals spans diverse fields, ranging from shielded coordination compounds over hydride to organometallic complexes for diverse applications. New developments pertain, not only to the lithium and magnesium chemistry with inspiring examples, such as heterobimetallic or heteroleptic complexes with special reactivity patterns, but the heavy s-block metals have progressively gained attention in various fields. Subvalent magnesium(I) derivatives are increasingly being used for reduction reactions, turbo-Grignard reagents show enhanced reactivity and tolerance toward functional groups, hydrides act as hydrogen storage materials, heavy Grignard reagents are available by straight forward procedures—just to name a few examples. Quantum chemical calculations deal with unique bonding situations and the relevance of d-orbital participation has been discussed to understand structure-reactivity relationships. Especially the complexes of the heavy alkaline earth metals are catalytically active in diverse reactions, promoting hydrofunctionalization reactions and Lewis acid catalysis. This Special Issue aims to highlight the structural and chemical diversity of s-block metal complexes, as well as the broad field of applications. 2021-02-12T02:42:34Z 2021-02-12T02:42:34Z 2017-12-06 12:48:40 2017 book 24752 9783038425892 9783038425908 https://directory.doabooks.org/handle/20.500.12854/58746 eng application/octet-stream Attribution-NonCommercial-NoDerivatives 4.0 International http://sci.fo/45m http://www.mdpi.com/books/pdfview/book/456 MDPI - Multidisciplinary Digital Publishing Institute 46cabcaa-dd94-4bfe-87b4-55023c1b36d0 9783038425892 9783038425908 VIII, 146 open access |
| spellingShingle | QD1-999 s-block metal coordination compounds Grignard-type reagents Lochmann-Schlosser bases heterobimetallic complexes s-block metal-mediated catalysis bonding in s-block complexes thema EDItEUR::P Mathematics and Science::PN Chemistry Matthias Westerhausen (Ed.) s-Block Metal Complexes |
| title | s-Block Metal Complexes |
| title_full | s-Block Metal Complexes |
| title_fullStr | s-Block Metal Complexes |
| title_full_unstemmed | s-Block Metal Complexes |
| title_short | s-Block Metal Complexes |
| title_sort | s block metal complexes |
| topic | QD1-999 s-block metal coordination compounds Grignard-type reagents Lochmann-Schlosser bases heterobimetallic complexes s-block metal-mediated catalysis bonding in s-block complexes thema EDItEUR::P Mathematics and Science::PN Chemistry |
| topic_facet | QD1-999 s-block metal coordination compounds Grignard-type reagents Lochmann-Schlosser bases heterobimetallic complexes s-block metal-mediated catalysis bonding in s-block complexes thema EDItEUR::P Mathematics and Science::PN Chemistry |
| url | 24752 |
| work_keys_str_mv | AT matthiaswesterhausened sblockmetalcomplexes |