Spin-Crossover Complexes
The spin-crossover (SCO) phenomenon originates from the intrinsic bistability of the d-electron configuration, created by the competition between ligand-field splitting and spin-pairing energies in a first coordination sphere of transition metal ions. Since Cambi’s visionary finding of the SCO pheno...
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| Formato: | Online |
| Idioma: | inglês |
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MDPI - Multidisciplinary Digital Publishing Institute
2021
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| Acesso em linha: | 27186 |
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| _version_ | 1869522047254659072 |
|---|---|
| author | Kazuyuki Takahashi (Ed.) |
| author_browse | Kazuyuki Takahashi (Ed.) |
| author_facet | Kazuyuki Takahashi (Ed.) |
| author_sort | Kazuyuki Takahashi (Ed.) |
| collection | Directory of Open Access Books |
| description | The spin-crossover (SCO) phenomenon originates from the intrinsic bistability of the d-electron configuration, created by the competition between ligand-field splitting and spin-pairing energies in a first coordination sphere of transition metal ions. Since Cambi’s visionary finding of the SCO phenomenon in 1931, considerable knowledge concerning syntheses, crystal structures, magnetic and thermodynamic properties, spectroscopies, molecular orbital calculations, and theories of SCO complexes has accumulated in a very large number of inorganic molecular coordination compounds, and, in addition, inorganic cobaltates and bioinorganic molecular systems. Recent studies which have focused on other electronic properties exhibited by SCO complexes themselves, control of molecular assemblies, and moreover, multifunctionalization of SCO complexes with either different electronic properties or porous frameworks will open the possibility toward future practical applications of SCO complexes. Thus, the fundamentals and applications of SCO complexes afford a very exciting research field in inorganic coordination chemistry and continues to attract growing attention on a wide range of relevant research fields. This Special Issue aims at collecting research and review contributions concerning recent advances in all aspects of SCO and related phenomena and disseminating this extensive knowledge with a broader audience by means of open access publishing. I invite you to contribute papers in the following research areas so that your research can impact the next generation trends in this promising field. |
| format | Online |
| id | doab-20.500.12854ir-59845 |
| institution | Directory of Open Access Books |
| language | eng |
| publishDate | 2021 |
| publishDateRange | 2021 |
| publishDateSort | 2021 |
| publisher | MDPI - Multidisciplinary Digital Publishing Institute |
| publisherStr | MDPI - Multidisciplinary Digital Publishing Institute |
| record_format | ojs |
| spelling | doab-20.500.12854ir-598452024-04-05T12:39:21Z Spin-Crossover Complexes Kazuyuki Takahashi (Ed.) QD1-999 Stimulus-induced Spin Transition Spin-Crossover (SCO) Crystal Engineering of SCO and related complexes Valence Tautomerism Multifunctionality of SCO and related complexes Charge-transfer-induced Spin Transition Ligand-driven Spin-state Conversion thema EDItEUR::P Mathematics and Science::PN Chemistry The spin-crossover (SCO) phenomenon originates from the intrinsic bistability of the d-electron configuration, created by the competition between ligand-field splitting and spin-pairing energies in a first coordination sphere of transition metal ions. Since Cambi’s visionary finding of the SCO phenomenon in 1931, considerable knowledge concerning syntheses, crystal structures, magnetic and thermodynamic properties, spectroscopies, molecular orbital calculations, and theories of SCO complexes has accumulated in a very large number of inorganic molecular coordination compounds, and, in addition, inorganic cobaltates and bioinorganic molecular systems. Recent studies which have focused on other electronic properties exhibited by SCO complexes themselves, control of molecular assemblies, and moreover, multifunctionalization of SCO complexes with either different electronic properties or porous frameworks will open the possibility toward future practical applications of SCO complexes. Thus, the fundamentals and applications of SCO complexes afford a very exciting research field in inorganic coordination chemistry and continues to attract growing attention on a wide range of relevant research fields. This Special Issue aims at collecting research and review contributions concerning recent advances in all aspects of SCO and related phenomena and disseminating this extensive knowledge with a broader audience by means of open access publishing. I invite you to contribute papers in the following research areas so that your research can impact the next generation trends in this promising field. 2021-02-12T04:17:01Z 2021-02-12T04:17:01Z 2018-06-26 14:01:59 2018 book 27186 9783038428268 9783038428251 https://directory.doabooks.org/handle/20.500.12854/59845 eng image/png Attribution-NonCommercial-NoDerivatives 4.0 International http://www.mdpi.com/books/pdfview/book/652 http://www.mdpi.com/books/pdfview/book/652 MDPI - Multidisciplinary Digital Publishing Institute 46cabcaa-dd94-4bfe-87b4-55023c1b36d0 9783038428268 9783038428251 VI, 200 open access |
| spellingShingle | QD1-999 Stimulus-induced Spin Transition Spin-Crossover (SCO) Crystal Engineering of SCO and related complexes Valence Tautomerism Multifunctionality of SCO and related complexes Charge-transfer-induced Spin Transition Ligand-driven Spin-state Conversion thema EDItEUR::P Mathematics and Science::PN Chemistry Kazuyuki Takahashi (Ed.) Spin-Crossover Complexes |
| title | Spin-Crossover Complexes |
| title_full | Spin-Crossover Complexes |
| title_fullStr | Spin-Crossover Complexes |
| title_full_unstemmed | Spin-Crossover Complexes |
| title_short | Spin-Crossover Complexes |
| title_sort | spin crossover complexes |
| topic | QD1-999 Stimulus-induced Spin Transition Spin-Crossover (SCO) Crystal Engineering of SCO and related complexes Valence Tautomerism Multifunctionality of SCO and related complexes Charge-transfer-induced Spin Transition Ligand-driven Spin-state Conversion thema EDItEUR::P Mathematics and Science::PN Chemistry |
| topic_facet | QD1-999 Stimulus-induced Spin Transition Spin-Crossover (SCO) Crystal Engineering of SCO and related complexes Valence Tautomerism Multifunctionality of SCO and related complexes Charge-transfer-induced Spin Transition Ligand-driven Spin-state Conversion thema EDItEUR::P Mathematics and Science::PN Chemistry |
| url | 27186 |
| work_keys_str_mv | AT kazuyukitakahashied spincrossovercomplexes |