Heterobimetallic [2.2]Paracyclophane Complexes and Their Application in Photoredox Catalysis
The most important goal of current chemistry research is to provide green and sustainable routes to compounds of interest. One way of addressing this is the use of abundant and inexpensive sources of energy to drive reactions, with the prime example being visible light in photoredox catalysis. One r...
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| Format: | Online |
| Langue: | anglais |
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Logos Verlag Berlin
2021
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| Accès en ligne: | ONIX_20210408_9783832550714_80 |
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| _version_ | 1869517288514781184 |
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| author | Knoll, Daniel |
| author_browse | Knoll, Daniel |
| author_facet | Knoll, Daniel |
| author_sort | Knoll, Daniel |
| collection | Directory of Open Access Books |
| description | The most important goal of current chemistry research is to provide green and sustainable routes to compounds of interest. One way of addressing this is the use of abundant and inexpensive sources of energy to drive reactions, with the prime example being visible light in photoredox catalysis. One recent promising approach is the use of heterobimetallic catalysts where two metals work in a cooperative fashion to achieve the desired transformation. However, these cooperative effects are poorly understood due to a lack of model complexes suitable for the intricate study of heterobimetallic complexes. In this work, [2.2]paracyclophane (PCP) is presented as a new platform on which to build distance-variable heterobimetallic complexes. The methods for the access to these synthetic targets are developed and investigated for their broader synthetic applicability. To demonstrate the potential of these complexes as catalysts, Au/Ru heterobimetallic complexes are evaluated regarding their performance in a dual photoredox catalytic arylative Meyer-Schuster rearrangement reaction. This reaction provides a very convenient and sustainable access α-arylated enones, an important building blocks for relevant pharmaceutical compounds. |
| format | Online |
| id | doab-20.500.12854ir-64438 |
| institution | Directory of Open Access Books |
| language | eng |
| publishDate | 2021 |
| publishDateRange | 2021 |
| publishDateSort | 2021 |
| publisher | Logos Verlag Berlin |
| publisherStr | Logos Verlag Berlin |
| record_format | ojs |
| spelling | doab-20.500.12854ir-644382024-04-05T12:40:30Z Heterobimetallic [2.2]Paracyclophane Complexes and Their Application in Photoredox Catalysis Knoll, Daniel Paracyclophane Catalysis Heterobimetallic Complexes Photocatalysis Cooperative Effects thema EDItEUR::P Mathematics and Science::PN Chemistry::PNF Analytical chemistry::PNFS Spectrum analysis, spectrochemistry, mass spectrometry The most important goal of current chemistry research is to provide green and sustainable routes to compounds of interest. One way of addressing this is the use of abundant and inexpensive sources of energy to drive reactions, with the prime example being visible light in photoredox catalysis. One recent promising approach is the use of heterobimetallic catalysts where two metals work in a cooperative fashion to achieve the desired transformation. However, these cooperative effects are poorly understood due to a lack of model complexes suitable for the intricate study of heterobimetallic complexes. In this work, [2.2]paracyclophane (PCP) is presented as a new platform on which to build distance-variable heterobimetallic complexes. The methods for the access to these synthetic targets are developed and investigated for their broader synthetic applicability. To demonstrate the potential of these complexes as catalysts, Au/Ru heterobimetallic complexes are evaluated regarding their performance in a dual photoredox catalytic arylative Meyer-Schuster rearrangement reaction. This reaction provides a very convenient and sustainable access α-arylated enones, an important building blocks for relevant pharmaceutical compounds. 2021-04-08T15:35:04Z 2021-04-08T15:35:04Z 2020 book ONIX_20210408_9783832550714_80 9783832550714 https://directory.doabooks.org/handle/20.500.12854/64438 eng Beiträge zur organischen Synthese image/jpeg Attribution-NonCommercial-NoDerivatives 4.0 International https://www.logos-verlag.de/cgi-bin/engbuchmid?isbn=5071&lng=eng&id= https://www.logos-verlag.de/ebooks/OA/978-3-8325-5071-4.pdf Logos Verlag Berlin Logos Verlag Berlin 10.30819/5071 10.30819/5071 04b263a1-7fba-4491-9eae-1c394ac42fc3 9783832550714 Logos Verlag Berlin 85 226 Berlin/Germany open access |
| spellingShingle | Paracyclophane Catalysis Heterobimetallic Complexes Photocatalysis Cooperative Effects thema EDItEUR::P Mathematics and Science::PN Chemistry::PNF Analytical chemistry::PNFS Spectrum analysis, spectrochemistry, mass spectrometry Knoll, Daniel Heterobimetallic [2.2]Paracyclophane Complexes and Their Application in Photoredox Catalysis |
| title | Heterobimetallic [2.2]Paracyclophane Complexes and Their Application in Photoredox Catalysis |
| title_full | Heterobimetallic [2.2]Paracyclophane Complexes and Their Application in Photoredox Catalysis |
| title_fullStr | Heterobimetallic [2.2]Paracyclophane Complexes and Their Application in Photoredox Catalysis |
| title_full_unstemmed | Heterobimetallic [2.2]Paracyclophane Complexes and Their Application in Photoredox Catalysis |
| title_short | Heterobimetallic [2.2]Paracyclophane Complexes and Their Application in Photoredox Catalysis |
| title_sort | heterobimetallic 2 2 paracyclophane complexes and their application in photoredox catalysis |
| topic | Paracyclophane Catalysis Heterobimetallic Complexes Photocatalysis Cooperative Effects thema EDItEUR::P Mathematics and Science::PN Chemistry::PNF Analytical chemistry::PNFS Spectrum analysis, spectrochemistry, mass spectrometry |
| topic_facet | Paracyclophane Catalysis Heterobimetallic Complexes Photocatalysis Cooperative Effects thema EDItEUR::P Mathematics and Science::PN Chemistry::PNF Analytical chemistry::PNFS Spectrum analysis, spectrochemistry, mass spectrometry |
| url | ONIX_20210408_9783832550714_80 |
| work_keys_str_mv | AT knolldaniel heterobimetallic22paracyclophanecomplexesandtheirapplicationinphotoredoxcatalysis |