Synthesis and Characterization of Ferroelectrics

The Special Issue on “Synthesis and Characterization of Ferroelectrics” reports on several physical properties of ferroelectric materials and their technological aspects. Different substitution mechanisms provide ideas toward future improvement of lead-free (Ba,Ca)(Zr,Ti)O3 piezoelectric ceramics, i...

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Publicado em: MDPI - Multidisciplinary Digital Publishing Institute 2021
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collection Directory of Open Access Books
description The Special Issue on “Synthesis and Characterization of Ferroelectrics” reports on several physical properties of ferroelectric materials and their technological aspects. Different substitution mechanisms provide ideas toward future improvement of lead-free (Ba,Ca)(Zr,Ti)O3 piezoelectric ceramics, including the electrocaloric effect, fluorescence, and energy storage. It is established that axial and radial element segregation differently influences electrical properties of 0.68Pb(Mg1/3Nb2/3)0.32PbTiO3 (PMN-32PT for short) single crystals. While the electrical properties along the axial direction strongly depend on the PbTiO3 content, the electrical properties along the axial direction are mainly determined by the ratio of Nb and Mg. On the other hand, Fe-substitution of PMN-32PT crystals lead to an enhancement of the coercive field due to wall pinning induced by charged defect dipoles. It is also found, that capacitors based on Pt/Na0.5Bi0.5TiO3/La0.5Sr0.5CoO3 thin films display good fatigue resistance and retention. Another lead-free thin film capacitor fabricated from Ba0.3Sr0.7Zr0.18Ti0.82 features a low leakage current density and high breakdown strength. Such capacitors are essential for energy storage. Furthermore, an enhanced electrocaloric effect on 0.73Pb(Mg1/3Nb2/3)0.27PbTiO3 single crystals is demonstrated. This effect is promising for novel solid-state cooling systems.
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id doab-20.500.12854ir-68326
institution Directory of Open Access Books
language eng
publishDate 2021
publishDateRange 2021
publishDateSort 2021
publisher MDPI - Multidisciplinary Digital Publishing Institute
publisherStr MDPI - Multidisciplinary Digital Publishing Institute
record_format ojs
spelling doab-20.500.12854ir-683262024-03-27T16:34:25Z Synthesis and Characterization of Ferroelectrics Dec, Jan PMN-32PT characterization segregation Bridgman technique ferroelectric materials piezoelectric ceramic lead-free PMN-32PT single crystal acceptor doping charged defects dielectric relaxation electrical conduction NBT epitaxial film ferroelectric properties ultraviolet light BSZT thin films capacitance properties RF magnetron sputtering PMN-PT single crystals P–E hysteresis loop electrocaloric effect Maxwell relation n/a thema EDItEUR::G Reference, Information and Interdisciplinary subjects::GP Research and information: general The Special Issue on “Synthesis and Characterization of Ferroelectrics” reports on several physical properties of ferroelectric materials and their technological aspects. Different substitution mechanisms provide ideas toward future improvement of lead-free (Ba,Ca)(Zr,Ti)O3 piezoelectric ceramics, including the electrocaloric effect, fluorescence, and energy storage. It is established that axial and radial element segregation differently influences electrical properties of 0.68Pb(Mg1/3Nb2/3)0.32PbTiO3 (PMN-32PT for short) single crystals. While the electrical properties along the axial direction strongly depend on the PbTiO3 content, the electrical properties along the axial direction are mainly determined by the ratio of Nb and Mg. On the other hand, Fe-substitution of PMN-32PT crystals lead to an enhancement of the coercive field due to wall pinning induced by charged defect dipoles. It is also found, that capacitors based on Pt/Na0.5Bi0.5TiO3/La0.5Sr0.5CoO3 thin films display good fatigue resistance and retention. Another lead-free thin film capacitor fabricated from Ba0.3Sr0.7Zr0.18Ti0.82 features a low leakage current density and high breakdown strength. Such capacitors are essential for energy storage. Furthermore, an enhanced electrocaloric effect on 0.73Pb(Mg1/3Nb2/3)0.27PbTiO3 single crystals is demonstrated. This effect is promising for novel solid-state cooling systems. 2021-05-01T15:06:59Z 2021-05-01T15:06:59Z 2021 book ONIX_20210501_9783039436552_70 9783039436552 9783039436569 https://directory.doabooks.org/handle/20.500.12854/68326 eng application/octet-stream Attribution 4.0 International https://mdpi.com/books/pdfview/book/3336 https://mdpi.com/books/pdfview/book/3336 MDPI - Multidisciplinary Digital Publishing Institute 10.3390/books978-3-03943-656-9 10.3390/books978-3-03943-656-9 46cabcaa-dd94-4bfe-87b4-55023c1b36d0 9783039436552 9783039436569 74 Basel, Switzerland open access
spellingShingle PMN-32PT
characterization
segregation
Bridgman technique
ferroelectric materials
piezoelectric
ceramic
lead-free
PMN-32PT single crystal
acceptor doping
charged defects
dielectric relaxation
electrical conduction
NBT epitaxial film
ferroelectric properties
ultraviolet light
BSZT thin films
capacitance properties
RF magnetron sputtering
PMN-PT
single crystals
P–E hysteresis loop
electrocaloric effect
Maxwell relation
n/a
thema EDItEUR::G Reference, Information and Interdisciplinary subjects::GP Research and information: general
Synthesis and Characterization of Ferroelectrics
title Synthesis and Characterization of Ferroelectrics
title_full Synthesis and Characterization of Ferroelectrics
title_fullStr Synthesis and Characterization of Ferroelectrics
title_full_unstemmed Synthesis and Characterization of Ferroelectrics
title_short Synthesis and Characterization of Ferroelectrics
title_sort synthesis and characterization of ferroelectrics
topic PMN-32PT
characterization
segregation
Bridgman technique
ferroelectric materials
piezoelectric
ceramic
lead-free
PMN-32PT single crystal
acceptor doping
charged defects
dielectric relaxation
electrical conduction
NBT epitaxial film
ferroelectric properties
ultraviolet light
BSZT thin films
capacitance properties
RF magnetron sputtering
PMN-PT
single crystals
P–E hysteresis loop
electrocaloric effect
Maxwell relation
n/a
thema EDItEUR::G Reference, Information and Interdisciplinary subjects::GP Research and information: general
topic_facet PMN-32PT
characterization
segregation
Bridgman technique
ferroelectric materials
piezoelectric
ceramic
lead-free
PMN-32PT single crystal
acceptor doping
charged defects
dielectric relaxation
electrical conduction
NBT epitaxial film
ferroelectric properties
ultraviolet light
BSZT thin films
capacitance properties
RF magnetron sputtering
PMN-PT
single crystals
P–E hysteresis loop
electrocaloric effect
Maxwell relation
n/a
thema EDItEUR::G Reference, Information and Interdisciplinary subjects::GP Research and information: general
url ONIX_20210501_9783039436552_70