Molecules from Side Reactions

The Special Issue “Molecules from Side Reactions” is a collection of papers reporting on the synthesis and characterization of the molecules that come from unexpected synthetic routes. This is the first example of a Special Issue based on such a topic, notwithstanding that all synthetic chemists hav...

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collection Directory of Open Access Books
description The Special Issue “Molecules from Side Reactions” is a collection of papers reporting on the synthesis and characterization of the molecules that come from unexpected synthetic routes. This is the first example of a Special Issue based on such a topic, notwithstanding that all synthetic chemists have isolated a side product during a chemical reaction. Instead of continuing to store the side products in the freezer, I have thought to give them the dignity of publication, making them available to the scientific community. The short manuscripts collected here respect the principle of “one compound per paper” and have the purpose of preserving the molecular diversity deriving from a chemical reaction. The molecular scaffolds are unexpected and intriguing, and could be useful starting points or intermediates for exploring novel reactions.
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institution Directory of Open Access Books
language eng
publishDate 2021
publishDateRange 2021
publishDateSort 2021
publisher MDPI - Multidisciplinary Digital Publishing Institute
publisherStr MDPI - Multidisciplinary Digital Publishing Institute
record_format ojs
spelling doab-20.500.12854ir-683342024-04-11T15:10:26Z Molecules from Side Reactions D’Errico, Stefano oxazole furan RORC reaction (E,Z)-isomerization nitration azaheterocycles N–C bond cleavage pyridine-imidazolium ribose psicose ketose rare sugar hydroxy methylation AICAR acadesine phosphorylation fluorination fluorinated nucleosides nucleoside analogues modified nucleosides chlorinated nucleosides AMPK organic synthesis bidentate directing groups benzamides chelation assistance bis-chelates C–H bond functionalization X-ray structure determination N′-acetylhydrazide 3-acetyl-2,3-dihydro-1,3,4-oxadiazole 1H-pyrazolo[3,4-b]pyridine heterocycle oxetane epoxide rearrangement carbohydrate C-glycosylation spiro-oxetane ester group migration glycosyl sulfoxide uronate thioglycoside oxidation mannose 8-Fluoro-2′-deoxyguanosine 19F NMR spectroscopy solid phase synthesis phosphoramidite muraymycins caprazamycins nucleosides uridine cyclization seven-membered rings conjugated diyne LAH reduction diacetal pent-1,2,3,4-tetraene intermediate ligand pyridine derivatives allenic compounds N-alkylation copper cyanide network guanidinium unexpected iminium cation n/a thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TB Technology: general issues::TBX History of engineering and technology The Special Issue “Molecules from Side Reactions” is a collection of papers reporting on the synthesis and characterization of the molecules that come from unexpected synthetic routes. This is the first example of a Special Issue based on such a topic, notwithstanding that all synthetic chemists have isolated a side product during a chemical reaction. Instead of continuing to store the side products in the freezer, I have thought to give them the dignity of publication, making them available to the scientific community. The short manuscripts collected here respect the principle of “one compound per paper” and have the purpose of preserving the molecular diversity deriving from a chemical reaction. The molecular scaffolds are unexpected and intriguing, and could be useful starting points or intermediates for exploring novel reactions. 2021-05-01T15:07:09Z 2021-05-01T15:07:09Z 2021 book ONIX_20210501_9783036500041_78 9783036500041 9783036500058 https://directory.doabooks.org/handle/20.500.12854/68334 eng application/octet-stream Attribution 4.0 International https://mdpi.com/books/pdfview/book/3344 https://mdpi.com/books/pdfview/book/3344 MDPI - Multidisciplinary Digital Publishing Institute 10.3390/books978-3-0365-0005-8 10.3390/books978-3-0365-0005-8 46cabcaa-dd94-4bfe-87b4-55023c1b36d0 9783036500041 9783036500058 100 Basel, Switzerland open access
spellingShingle oxazole
furan
RORC reaction
(E,Z)-isomerization
nitration
azaheterocycles
N–C bond cleavage
pyridine-imidazolium
ribose
psicose
ketose
rare sugar
hydroxy methylation
AICAR
acadesine
phosphorylation
fluorination
fluorinated nucleosides
nucleoside analogues
modified nucleosides
chlorinated nucleosides
AMPK
organic synthesis
bidentate directing groups
benzamides
chelation assistance
bis-chelates
C–H bond functionalization
X-ray structure determination
N′-acetylhydrazide
3-acetyl-2,3-dihydro-1,3,4-oxadiazole
1H-pyrazolo[3,4-b]pyridine
heterocycle
oxetane
epoxide
rearrangement
carbohydrate
C-glycosylation
spiro-oxetane
ester group migration
glycosyl sulfoxide
uronate
thioglycoside oxidation
mannose
8-Fluoro-2′-deoxyguanosine
19F NMR spectroscopy
solid phase synthesis
phosphoramidite
muraymycins
caprazamycins
nucleosides
uridine
cyclization
seven-membered rings
conjugated diyne
LAH reduction
diacetal
pent-1,2,3,4-tetraene intermediate
ligand
pyridine derivatives
allenic compounds
N-alkylation
copper
cyanide
network
guanidinium
unexpected iminium cation
n/a
thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TB Technology: general issues::TBX History of engineering and technology
Molecules from Side Reactions
title Molecules from Side Reactions
title_full Molecules from Side Reactions
title_fullStr Molecules from Side Reactions
title_full_unstemmed Molecules from Side Reactions
title_short Molecules from Side Reactions
title_sort molecules from side reactions
topic oxazole
furan
RORC reaction
(E,Z)-isomerization
nitration
azaheterocycles
N–C bond cleavage
pyridine-imidazolium
ribose
psicose
ketose
rare sugar
hydroxy methylation
AICAR
acadesine
phosphorylation
fluorination
fluorinated nucleosides
nucleoside analogues
modified nucleosides
chlorinated nucleosides
AMPK
organic synthesis
bidentate directing groups
benzamides
chelation assistance
bis-chelates
C–H bond functionalization
X-ray structure determination
N′-acetylhydrazide
3-acetyl-2,3-dihydro-1,3,4-oxadiazole
1H-pyrazolo[3,4-b]pyridine
heterocycle
oxetane
epoxide
rearrangement
carbohydrate
C-glycosylation
spiro-oxetane
ester group migration
glycosyl sulfoxide
uronate
thioglycoside oxidation
mannose
8-Fluoro-2′-deoxyguanosine
19F NMR spectroscopy
solid phase synthesis
phosphoramidite
muraymycins
caprazamycins
nucleosides
uridine
cyclization
seven-membered rings
conjugated diyne
LAH reduction
diacetal
pent-1,2,3,4-tetraene intermediate
ligand
pyridine derivatives
allenic compounds
N-alkylation
copper
cyanide
network
guanidinium
unexpected iminium cation
n/a
thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TB Technology: general issues::TBX History of engineering and technology
topic_facet oxazole
furan
RORC reaction
(E,Z)-isomerization
nitration
azaheterocycles
N–C bond cleavage
pyridine-imidazolium
ribose
psicose
ketose
rare sugar
hydroxy methylation
AICAR
acadesine
phosphorylation
fluorination
fluorinated nucleosides
nucleoside analogues
modified nucleosides
chlorinated nucleosides
AMPK
organic synthesis
bidentate directing groups
benzamides
chelation assistance
bis-chelates
C–H bond functionalization
X-ray structure determination
N′-acetylhydrazide
3-acetyl-2,3-dihydro-1,3,4-oxadiazole
1H-pyrazolo[3,4-b]pyridine
heterocycle
oxetane
epoxide
rearrangement
carbohydrate
C-glycosylation
spiro-oxetane
ester group migration
glycosyl sulfoxide
uronate
thioglycoside oxidation
mannose
8-Fluoro-2′-deoxyguanosine
19F NMR spectroscopy
solid phase synthesis
phosphoramidite
muraymycins
caprazamycins
nucleosides
uridine
cyclization
seven-membered rings
conjugated diyne
LAH reduction
diacetal
pent-1,2,3,4-tetraene intermediate
ligand
pyridine derivatives
allenic compounds
N-alkylation
copper
cyanide
network
guanidinium
unexpected iminium cation
n/a
thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TB Technology: general issues::TBX History of engineering and technology
url ONIX_20210501_9783036500041_78