Advanced Catalysis in Hydrogen Production from Formic Acid and Methanol

This Special Issue is related to studies of the hydrogen production from formic acid decomposition. It is based on five research papers and two reviews. The reviews discuss the liquid phase formic acid decomposition over bimetallic (PdAg), molecular (Ru, Ir, Fe, Co), and heterogenized molecular cata...

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collection Directory of Open Access Books
description This Special Issue is related to studies of the hydrogen production from formic acid decomposition. It is based on five research papers and two reviews. The reviews discuss the liquid phase formic acid decomposition over bimetallic (PdAg), molecular (Ru, Ir, Fe, Co), and heterogenized molecular catalysts. The gas-phase reaction is studied over highly dispersed Pd, Pt, Au, Cu, and Ni supported catalysts. It is shown that the nature of the catalyst’s support plays an important role for the reaction. Thus, N-doping of the carbon support provides a significant promotional effect. One of the reasons for the high activity of the N-doped catalysts is the formation of single-atom active sites stabilized by pyridinic N species present in the support. It is demonstrated that carbon materials can be N-doped in different ways. It can be performed either directly from N-containing compounds during the carbon synthesis or by a post-synthetic deposition of N-containing compounds on the carbon support with known properties. The Issue could be useful for specialists in catalysis and nanomaterials as well as for graduate students studying chemistry and chemical engineering. The reported results can be applied for development of catalysts for the hydrogen production from different liquid organic hydrogen carriers.
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publisherStr MDPI - Multidisciplinary Digital Publishing Institute
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spelling doab-20.500.12854ir-686402024-04-09T23:15:28Z Advanced Catalysis in Hydrogen Production from Formic Acid and Methanol Bulushev, Dmitri A. formic acid decomposition hydrogen production CuO-CeO2/γ-Al2O3 multifuel processor copper catalyst oxygenates fuel cell Pd/C melamine g-C3N4 bipyridine phenanthroline N-doped carbon hydrogen formic acid platinum nitrogen doped carbon nanotubes carbon nanofibers heterogeneous catalysts bimetallic nanoparticles PdAg AgPd alloy nickel catalyst porous carbon support nitrogen doping hydrogen energetics hydrogen carrier formic acid dehydrogenation supported gold catalysts formic formate hybrid functionalization co-catalyst additive amine molecular catalyst nanocatalyst nano co-catalyst thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TB Technology: general issues This Special Issue is related to studies of the hydrogen production from formic acid decomposition. It is based on five research papers and two reviews. The reviews discuss the liquid phase formic acid decomposition over bimetallic (PdAg), molecular (Ru, Ir, Fe, Co), and heterogenized molecular catalysts. The gas-phase reaction is studied over highly dispersed Pd, Pt, Au, Cu, and Ni supported catalysts. It is shown that the nature of the catalyst’s support plays an important role for the reaction. Thus, N-doping of the carbon support provides a significant promotional effect. One of the reasons for the high activity of the N-doped catalysts is the formation of single-atom active sites stabilized by pyridinic N species present in the support. It is demonstrated that carbon materials can be N-doped in different ways. It can be performed either directly from N-containing compounds during the carbon synthesis or by a post-synthetic deposition of N-containing compounds on the carbon support with known properties. The Issue could be useful for specialists in catalysis and nanomaterials as well as for graduate students studying chemistry and chemical engineering. The reported results can be applied for development of catalysts for the hydrogen production from different liquid organic hydrogen carriers. 2021-05-01T15:16:28Z 2021-05-01T15:16:28Z 2020 book ONIX_20210501_9783039363803_386 9783039363803 9783039363810 https://directory.doabooks.org/handle/20.500.12854/68640 eng application/octet-stream Attribution 4.0 International https://mdpi.com/books/pdfview/book/2402 https://mdpi.com/books/pdfview/book/2402 MDPI - Multidisciplinary Digital Publishing Institute 10.3390/books978-3-03936-381-0 10.3390/books978-3-03936-381-0 46cabcaa-dd94-4bfe-87b4-55023c1b36d0 9783039363803 9783039363810 122 Basel, Switzerland open access
spellingShingle formic acid decomposition
hydrogen production
CuO-CeO2/γ-Al2O3
multifuel processor
copper catalyst
oxygenates
fuel cell
Pd/C
melamine
g-C3N4
bipyridine
phenanthroline
N-doped carbon
hydrogen
formic acid
platinum
nitrogen doped
carbon nanotubes
carbon nanofibers
heterogeneous catalysts
bimetallic nanoparticles
PdAg
AgPd
alloy
nickel catalyst
porous carbon support
nitrogen doping
hydrogen energetics
hydrogen carrier
formic acid dehydrogenation
supported gold catalysts
formic
formate
hybrid
functionalization
co-catalyst
additive
amine
molecular catalyst
nanocatalyst
nano co-catalyst
thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TB Technology: general issues
Advanced Catalysis in Hydrogen Production from Formic Acid and Methanol
title Advanced Catalysis in Hydrogen Production from Formic Acid and Methanol
title_full Advanced Catalysis in Hydrogen Production from Formic Acid and Methanol
title_fullStr Advanced Catalysis in Hydrogen Production from Formic Acid and Methanol
title_full_unstemmed Advanced Catalysis in Hydrogen Production from Formic Acid and Methanol
title_short Advanced Catalysis in Hydrogen Production from Formic Acid and Methanol
title_sort advanced catalysis in hydrogen production from formic acid and methanol
topic formic acid decomposition
hydrogen production
CuO-CeO2/γ-Al2O3
multifuel processor
copper catalyst
oxygenates
fuel cell
Pd/C
melamine
g-C3N4
bipyridine
phenanthroline
N-doped carbon
hydrogen
formic acid
platinum
nitrogen doped
carbon nanotubes
carbon nanofibers
heterogeneous catalysts
bimetallic nanoparticles
PdAg
AgPd
alloy
nickel catalyst
porous carbon support
nitrogen doping
hydrogen energetics
hydrogen carrier
formic acid dehydrogenation
supported gold catalysts
formic
formate
hybrid
functionalization
co-catalyst
additive
amine
molecular catalyst
nanocatalyst
nano co-catalyst
thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TB Technology: general issues
topic_facet formic acid decomposition
hydrogen production
CuO-CeO2/γ-Al2O3
multifuel processor
copper catalyst
oxygenates
fuel cell
Pd/C
melamine
g-C3N4
bipyridine
phenanthroline
N-doped carbon
hydrogen
formic acid
platinum
nitrogen doped
carbon nanotubes
carbon nanofibers
heterogeneous catalysts
bimetallic nanoparticles
PdAg
AgPd
alloy
nickel catalyst
porous carbon support
nitrogen doping
hydrogen energetics
hydrogen carrier
formic acid dehydrogenation
supported gold catalysts
formic
formate
hybrid
functionalization
co-catalyst
additive
amine
molecular catalyst
nanocatalyst
nano co-catalyst
thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TB Technology: general issues
url ONIX_20210501_9783039363803_386