Iron and Cobalt Catalysts
Since the turn of the last century when the field of catalysis was born, iron and cobalt have been key players in numerous catalysis processes. These metals, due to their ability to activate CO and CH, haev a major economic impact worldwide. Several industrial processes and synthetic routes use thes...
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| Taal: | Engels |
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MDPI - Multidisciplinary Digital Publishing Institute
2021
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| Online toegang: | ONIX_20210501_9783039283880_419 |
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| description | Since the turn of the last century when the field of catalysis was born, iron and cobalt have been key players in numerous catalysis processes. These metals, due to their ability to activate CO and CH, haev a major economic impact worldwide. Several industrial processes and synthetic routes use these metals: biomass-to-liquids (BTL), coal-to-liquids (CTL), natural gas-to-liquids (GTL), water-gas-shift, alcohol synthesis, alcohol steam reforming, polymerization processes, cross-coupling reactions, and photocatalyst activated reactions. A vast number of materials are produced from these processes, including oil, lubricants, waxes, diesel and jet fuels, hydrogen (e.g., fuel cell applications), gasoline, rubbers, plastics, alcohols, pharmaceuticals, agrochemicals, feed-stock chemicals, and other alternative materials. However, given the true complexities of the variables involved in these processes, many key mechanistic issues are still not fully defined or understood. This Special Issue of Catalysis will be a collaborative effort to combine current catalysis research on these metals from experimental and theoretical perspectives on both heterogeneous and homogeneous catalysts. We welcome contributions from the catalysis community on catalyst characterization, kinetics, reaction mechanism, reactor development, theoretical modeling, and surface science. |
| format | Online |
| id | doab-20.500.12854ir-68673 |
| institution | Directory of Open Access Books |
| language | eng |
| publishDate | 2021 |
| publishDateRange | 2021 |
| publishDateSort | 2021 |
| publisher | MDPI - Multidisciplinary Digital Publishing Institute |
| publisherStr | MDPI - Multidisciplinary Digital Publishing Institute |
| record_format | ojs |
| spelling | doab-20.500.12854ir-686732024-04-09T23:15:52Z Iron and Cobalt Catalysts Shafer, Wilson D Jacobs, Gary polynuclear cobalt complexes water oxidation artificial photosynthesis Fe/Cu catalytic-ceramic-filler nitrobenzene compounds wastewater pilot-scale test biodegradability-improvement Fischer–Tropsch synthesis (FTS) oxygenates iron cobalt ruthenium Anderson-Schulz-Flory (ASF) distribution Fischer–Tropsch catalyst deactivation potassium liquid-phase catalytic oxidation limonene carvone zeolitic imidazolate frameworks Fischer-Tropsch synthesis chain growth CO insertion kinetic isotope effect DFT hydrogenation of CO iron catalysts syngas monometallic iron catalysts Fischer–Tropsch product distribution reaction mechanism catalysis process synthesis and design energy conversion iron–cobalt bimetal catalysts electrochemical application hydrogen evolution oxygen evolution oxygen reduction RWGS iron oxides CO2 conversion gas-switching Synthetic natural gas (SNG) Cobalt Iron C2–C4 hydrocarbons paraffin ratio asymmetric hydrogenation homogeneous catalysis structural design conformational analysis NMR spectroscopy alumina strong metal support interactions CO2 hydrogenation pressure temperature cobalt carboxylate coating autoxidation alkyd siccative polymerization manganese Fischer–Tropsch synthesis modeling kinetics Co Al2O3 Pt Cd In Sn hydrocarbon selectivity synergic effect GTL additives reducibility XANES mesoporous silica based catalysts kinetic studies 3-D printed microchannel microreactor cobalt–nickel nanoparticles cobalt–nickel alloys nickel HAADF-STEM TPR-EXAFS/XANES CO hydrogenation CSTR n/a thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TB Technology: general issues Since the turn of the last century when the field of catalysis was born, iron and cobalt have been key players in numerous catalysis processes. These metals, due to their ability to activate CO and CH, haev a major economic impact worldwide. Several industrial processes and synthetic routes use these metals: biomass-to-liquids (BTL), coal-to-liquids (CTL), natural gas-to-liquids (GTL), water-gas-shift, alcohol synthesis, alcohol steam reforming, polymerization processes, cross-coupling reactions, and photocatalyst activated reactions. A vast number of materials are produced from these processes, including oil, lubricants, waxes, diesel and jet fuels, hydrogen (e.g., fuel cell applications), gasoline, rubbers, plastics, alcohols, pharmaceuticals, agrochemicals, feed-stock chemicals, and other alternative materials. However, given the true complexities of the variables involved in these processes, many key mechanistic issues are still not fully defined or understood. This Special Issue of Catalysis will be a collaborative effort to combine current catalysis research on these metals from experimental and theoretical perspectives on both heterogeneous and homogeneous catalysts. We welcome contributions from the catalysis community on catalyst characterization, kinetics, reaction mechanism, reactor development, theoretical modeling, and surface science. 2021-05-01T15:26:34Z 2021-05-01T15:26:34Z 2020 book ONIX_20210501_9783039283880_419 9783039283880 9783039283897 https://directory.doabooks.org/handle/20.500.12854/68673 eng application/octet-stream Attribution 4.0 International https://mdpi.com/books/pdfview/book/2436 https://mdpi.com/books/pdfview/book/2436 MDPI - Multidisciplinary Digital Publishing Institute 10.3390/books978-3-03928-389-7 10.3390/books978-3-03928-389-7 46cabcaa-dd94-4bfe-87b4-55023c1b36d0 9783039283880 9783039283897 414 Basel, Switzerland open access |
| spellingShingle | polynuclear cobalt complexes water oxidation artificial photosynthesis Fe/Cu catalytic-ceramic-filler nitrobenzene compounds wastewater pilot-scale test biodegradability-improvement Fischer–Tropsch synthesis (FTS) oxygenates iron cobalt ruthenium Anderson-Schulz-Flory (ASF) distribution Fischer–Tropsch catalyst deactivation potassium liquid-phase catalytic oxidation limonene carvone zeolitic imidazolate frameworks Fischer-Tropsch synthesis chain growth CO insertion kinetic isotope effect DFT hydrogenation of CO iron catalysts syngas monometallic iron catalysts Fischer–Tropsch product distribution reaction mechanism catalysis process synthesis and design energy conversion iron–cobalt bimetal catalysts electrochemical application hydrogen evolution oxygen evolution oxygen reduction RWGS iron oxides CO2 conversion gas-switching Synthetic natural gas (SNG) Cobalt Iron C2–C4 hydrocarbons paraffin ratio asymmetric hydrogenation homogeneous catalysis structural design conformational analysis NMR spectroscopy alumina strong metal support interactions CO2 hydrogenation pressure temperature cobalt carboxylate coating autoxidation alkyd siccative polymerization manganese Fischer–Tropsch synthesis modeling kinetics Co Al2O3 Pt Cd In Sn hydrocarbon selectivity synergic effect GTL additives reducibility XANES mesoporous silica based catalysts kinetic studies 3-D printed microchannel microreactor cobalt–nickel nanoparticles cobalt–nickel alloys nickel HAADF-STEM TPR-EXAFS/XANES CO hydrogenation CSTR n/a thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TB Technology: general issues Iron and Cobalt Catalysts |
| title | Iron and Cobalt Catalysts |
| title_full | Iron and Cobalt Catalysts |
| title_fullStr | Iron and Cobalt Catalysts |
| title_full_unstemmed | Iron and Cobalt Catalysts |
| title_short | Iron and Cobalt Catalysts |
| title_sort | iron and cobalt catalysts |
| topic | polynuclear cobalt complexes water oxidation artificial photosynthesis Fe/Cu catalytic-ceramic-filler nitrobenzene compounds wastewater pilot-scale test biodegradability-improvement Fischer–Tropsch synthesis (FTS) oxygenates iron cobalt ruthenium Anderson-Schulz-Flory (ASF) distribution Fischer–Tropsch catalyst deactivation potassium liquid-phase catalytic oxidation limonene carvone zeolitic imidazolate frameworks Fischer-Tropsch synthesis chain growth CO insertion kinetic isotope effect DFT hydrogenation of CO iron catalysts syngas monometallic iron catalysts Fischer–Tropsch product distribution reaction mechanism catalysis process synthesis and design energy conversion iron–cobalt bimetal catalysts electrochemical application hydrogen evolution oxygen evolution oxygen reduction RWGS iron oxides CO2 conversion gas-switching Synthetic natural gas (SNG) Cobalt Iron C2–C4 hydrocarbons paraffin ratio asymmetric hydrogenation homogeneous catalysis structural design conformational analysis NMR spectroscopy alumina strong metal support interactions CO2 hydrogenation pressure temperature cobalt carboxylate coating autoxidation alkyd siccative polymerization manganese Fischer–Tropsch synthesis modeling kinetics Co Al2O3 Pt Cd In Sn hydrocarbon selectivity synergic effect GTL additives reducibility XANES mesoporous silica based catalysts kinetic studies 3-D printed microchannel microreactor cobalt–nickel nanoparticles cobalt–nickel alloys nickel HAADF-STEM TPR-EXAFS/XANES CO hydrogenation CSTR n/a thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TB Technology: general issues |
| topic_facet | polynuclear cobalt complexes water oxidation artificial photosynthesis Fe/Cu catalytic-ceramic-filler nitrobenzene compounds wastewater pilot-scale test biodegradability-improvement Fischer–Tropsch synthesis (FTS) oxygenates iron cobalt ruthenium Anderson-Schulz-Flory (ASF) distribution Fischer–Tropsch catalyst deactivation potassium liquid-phase catalytic oxidation limonene carvone zeolitic imidazolate frameworks Fischer-Tropsch synthesis chain growth CO insertion kinetic isotope effect DFT hydrogenation of CO iron catalysts syngas monometallic iron catalysts Fischer–Tropsch product distribution reaction mechanism catalysis process synthesis and design energy conversion iron–cobalt bimetal catalysts electrochemical application hydrogen evolution oxygen evolution oxygen reduction RWGS iron oxides CO2 conversion gas-switching Synthetic natural gas (SNG) Cobalt Iron C2–C4 hydrocarbons paraffin ratio asymmetric hydrogenation homogeneous catalysis structural design conformational analysis NMR spectroscopy alumina strong metal support interactions CO2 hydrogenation pressure temperature cobalt carboxylate coating autoxidation alkyd siccative polymerization manganese Fischer–Tropsch synthesis modeling kinetics Co Al2O3 Pt Cd In Sn hydrocarbon selectivity synergic effect GTL additives reducibility XANES mesoporous silica based catalysts kinetic studies 3-D printed microchannel microreactor cobalt–nickel nanoparticles cobalt–nickel alloys nickel HAADF-STEM TPR-EXAFS/XANES CO hydrogenation CSTR n/a thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TB Technology: general issues |
| url | ONIX_20210501_9783039283880_419 |