Recent Advances in Iron Catalysis
Transition metal-catalyzed reactions play a key role in many transformations of synthetic organic chemistry. For most of these reactions, noble metals, for example, palladium, have been used as catalysts. Over the last two decades, more and more first row transition metals have been applied as catal...
I tiakina i:
| Hōputu: | Online |
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| Reo: | Ingarihi |
| I whakaputaina: |
MDPI - Multidisciplinary Digital Publishing Institute
2021
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| Urunga tuihono: | ONIX_20210501_9783039431182_878 |
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Kāore He Tūtohu, Me noho koe te mea tuatahi ki te tūtohu i tēnei pūkete!
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| collection | Directory of Open Access Books |
| description | Transition metal-catalyzed reactions play a key role in many transformations of synthetic organic chemistry. For most of these reactions, noble metals, for example, palladium, have been used as catalysts. Over the last two decades, more and more first row transition metals have been applied as catalysts for organic reactions, with iron taking the center stage. The driving forces behind this development are not only the high costs for the noble metals but also their toxicity. Iron is the most abundant transition metal in the Earth’s crust, and thus, it is considerably cheaper than the precious noble metals. Moreover, iron compounds are involved in many biological processes, and thus, iron exhibits a low toxicity. Because of this low toxicity, iron-catalyzed reactions are important for an environmentally benign sustainable chemistry. However, iron catalysts are not only investigated to replace noble metals; they offer many applications in synthesis beyond those of classical noble metal catalysts. Several articles of the present book emphasize the complementarity of iron-catalyzed reactions as compared to reactions catalyzed by noble metals. The book shows intriguing recent developments and the current standing of iron-catalyzed reactions as well as applications to organic synthesis. |
| format | Online |
| id | doab-20.500.12854ir-69132 |
| institution | Directory of Open Access Books |
| language | eng |
| publishDate | 2021 |
| publishDateRange | 2021 |
| publishDateSort | 2021 |
| publisher | MDPI - Multidisciplinary Digital Publishing Institute |
| publisherStr | MDPI - Multidisciplinary Digital Publishing Institute |
| record_format | ojs |
| spelling | doab-20.500.12854ir-691322024-03-27T16:34:31Z Recent Advances in Iron Catalysis Knölker, Hans-Joachim iron cross-coupling aryl esters C–O activation Fe-catalysis Kumada cross-coupling iron complexes hydrogen transfer reductive amination alcohols amines decarbonylation alkylation spirocyclization aldehyde cinnamamide iron catalysis bis-(aryl)manganese alkenyl halides ate iron(II) complex asymmetric catalysis nitrogen ligand oxidative coupling BINOL synthesis carbene diazoalkane C-H functionalization catalysis borylation Iron C-H functionalisation pinacolborane photochemistry amidation iron(III) chloride amides esters solvent-free iron-catalysis carboazidation β-methyl scission radical DFT organic synthesis C-H activation C-C coupling α-alkenylation dehydrogenative coupling sustainability naphthidines fluorescence iron catalyst ATRP controlled radical polymerization external stimuli asymmetric transfer hydrogenation density functional theory bifunctional catalyst haloalkane coupling Grignard reagent FeI/FeII/FeIII mechanism thema EDItEUR::G Reference, Information and Interdisciplinary subjects::GP Research and information: general Transition metal-catalyzed reactions play a key role in many transformations of synthetic organic chemistry. For most of these reactions, noble metals, for example, palladium, have been used as catalysts. Over the last two decades, more and more first row transition metals have been applied as catalysts for organic reactions, with iron taking the center stage. The driving forces behind this development are not only the high costs for the noble metals but also their toxicity. Iron is the most abundant transition metal in the Earth’s crust, and thus, it is considerably cheaper than the precious noble metals. Moreover, iron compounds are involved in many biological processes, and thus, iron exhibits a low toxicity. Because of this low toxicity, iron-catalyzed reactions are important for an environmentally benign sustainable chemistry. However, iron catalysts are not only investigated to replace noble metals; they offer many applications in synthesis beyond those of classical noble metal catalysts. Several articles of the present book emphasize the complementarity of iron-catalyzed reactions as compared to reactions catalyzed by noble metals. The book shows intriguing recent developments and the current standing of iron-catalyzed reactions as well as applications to organic synthesis. 2021-05-01T15:41:50Z 2021-05-01T15:41:50Z 2020 book ONIX_20210501_9783039431182_878 9783039431182 9783039431199 https://directory.doabooks.org/handle/20.500.12854/69132 eng application/octet-stream Attribution 4.0 International https://mdpi.com/books/pdfview/book/2904 https://mdpi.com/books/pdfview/book/2904 MDPI - Multidisciplinary Digital Publishing Institute 10.3390/books978-3-03943-119-9 10.3390/books978-3-03943-119-9 46cabcaa-dd94-4bfe-87b4-55023c1b36d0 9783039431182 9783039431199 224 Basel, Switzerland open access |
| spellingShingle | iron cross-coupling aryl esters C–O activation Fe-catalysis Kumada cross-coupling iron complexes hydrogen transfer reductive amination alcohols amines decarbonylation alkylation spirocyclization aldehyde cinnamamide iron catalysis bis-(aryl)manganese alkenyl halides ate iron(II) complex asymmetric catalysis nitrogen ligand oxidative coupling BINOL synthesis carbene diazoalkane C-H functionalization catalysis borylation Iron C-H functionalisation pinacolborane photochemistry amidation iron(III) chloride amides esters solvent-free iron-catalysis carboazidation β-methyl scission radical DFT organic synthesis C-H activation C-C coupling α-alkenylation dehydrogenative coupling sustainability naphthidines fluorescence iron catalyst ATRP controlled radical polymerization external stimuli asymmetric transfer hydrogenation density functional theory bifunctional catalyst haloalkane coupling Grignard reagent FeI/FeII/FeIII mechanism thema EDItEUR::G Reference, Information and Interdisciplinary subjects::GP Research and information: general Recent Advances in Iron Catalysis |
| title | Recent Advances in Iron Catalysis |
| title_full | Recent Advances in Iron Catalysis |
| title_fullStr | Recent Advances in Iron Catalysis |
| title_full_unstemmed | Recent Advances in Iron Catalysis |
| title_short | Recent Advances in Iron Catalysis |
| title_sort | recent advances in iron catalysis |
| topic | iron cross-coupling aryl esters C–O activation Fe-catalysis Kumada cross-coupling iron complexes hydrogen transfer reductive amination alcohols amines decarbonylation alkylation spirocyclization aldehyde cinnamamide iron catalysis bis-(aryl)manganese alkenyl halides ate iron(II) complex asymmetric catalysis nitrogen ligand oxidative coupling BINOL synthesis carbene diazoalkane C-H functionalization catalysis borylation Iron C-H functionalisation pinacolborane photochemistry amidation iron(III) chloride amides esters solvent-free iron-catalysis carboazidation β-methyl scission radical DFT organic synthesis C-H activation C-C coupling α-alkenylation dehydrogenative coupling sustainability naphthidines fluorescence iron catalyst ATRP controlled radical polymerization external stimuli asymmetric transfer hydrogenation density functional theory bifunctional catalyst haloalkane coupling Grignard reagent FeI/FeII/FeIII mechanism thema EDItEUR::G Reference, Information and Interdisciplinary subjects::GP Research and information: general |
| topic_facet | iron cross-coupling aryl esters C–O activation Fe-catalysis Kumada cross-coupling iron complexes hydrogen transfer reductive amination alcohols amines decarbonylation alkylation spirocyclization aldehyde cinnamamide iron catalysis bis-(aryl)manganese alkenyl halides ate iron(II) complex asymmetric catalysis nitrogen ligand oxidative coupling BINOL synthesis carbene diazoalkane C-H functionalization catalysis borylation Iron C-H functionalisation pinacolborane photochemistry amidation iron(III) chloride amides esters solvent-free iron-catalysis carboazidation β-methyl scission radical DFT organic synthesis C-H activation C-C coupling α-alkenylation dehydrogenative coupling sustainability naphthidines fluorescence iron catalyst ATRP controlled radical polymerization external stimuli asymmetric transfer hydrogenation density functional theory bifunctional catalyst haloalkane coupling Grignard reagent FeI/FeII/FeIII mechanism thema EDItEUR::G Reference, Information and Interdisciplinary subjects::GP Research and information: general |
| url | ONIX_20210501_9783039431182_878 |