Application of New Nanoparticle Structures as Catalysts

Catalysts are made of nanoparticles of metals, metal oxides, and other compounds that may act as active phases, support the latter, or a combination of both. The initial incentive to reduce as much as possible, up to the nano-scale, the size of the particles of active catalyst components is to maxim...

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יצא לאור: MDPI - Multidisciplinary Digital Publishing Institute 2021
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גישה מקוונת:ONIX_20210501_9783039432509_970
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collection Directory of Open Access Books
description Catalysts are made of nanoparticles of metals, metal oxides, and other compounds that may act as active phases, support the latter, or a combination of both. The initial incentive to reduce as much as possible, up to the nano-scale, the size of the particles of active catalyst components is to maximize the surface area exposed to reactants, thus minimizing the specific cost per function and increasing the rate of conversion of feedstocks to products in relatively simple reactions. Nowadays, the interest in nanocatalyst developments has shifted to an emphasis on improving the selectivity of catalysts, allowing one to obtain desirable reactions in more complex synthetic processes. Thus, new generations of nanocatalysts should be designed at the molecular level to display well-defined structural characteristics, in terms of size, shapes, hierarchical porosity, and morphologies, as well as with controlled chemical composition. The development of efficient nanocatalysts supposes the characterization of their various surface active sites at the nanometer scale, which is focused on establishing synthesis–structure–performance relationships.
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spelling doab-20.500.12854ir-692242024-03-28T03:32:48Z Application of New Nanoparticle Structures as Catalysts Guerrero Ruiz, Antonio Rodríguez-Ramos, Inmaculada plasmonic photocatalyst metal nanoparticle N–TiO2 nanocomposites photocatalytic selective oxidation heterogeneous catalysis transition metal nitrides hydrogen production formic acid decomposition nickel catalyst calcium oxide promoter silica support Iron-based perovskites copper NO oxidation to NO2 NO2-assisted diesel soot oxidation soot oxidation under GDI exhaust conditions aqueous-phase reforming nickel ceria zirconia calcium yttrium methanol graphite reduced graphene oxide nitrogen-doped reduced graphene oxide exfoliation oxygen reduction reaction electrocatalysis UiO-66 iron cobalt nanocatalyst CO oxidation COProx methane oxidation catalysis formaldehyde magnetite iron oxide Fe3O4 palladium Pd silver Ag low-temperature activity nanocomposite Raman TG in air TG in hydrogen XRD electron microscopy EDS coordination polymers methane storage XRD crystallinity measurements mechanical shaping compaction VAM gas separation MOF pelletization catalysts dimerization isobutene olefins n/a thema EDItEUR::G Reference, Information and Interdisciplinary subjects::GP Research and information: general Catalysts are made of nanoparticles of metals, metal oxides, and other compounds that may act as active phases, support the latter, or a combination of both. The initial incentive to reduce as much as possible, up to the nano-scale, the size of the particles of active catalyst components is to maximize the surface area exposed to reactants, thus minimizing the specific cost per function and increasing the rate of conversion of feedstocks to products in relatively simple reactions. Nowadays, the interest in nanocatalyst developments has shifted to an emphasis on improving the selectivity of catalysts, allowing one to obtain desirable reactions in more complex synthetic processes. Thus, new generations of nanocatalysts should be designed at the molecular level to display well-defined structural characteristics, in terms of size, shapes, hierarchical porosity, and morphologies, as well as with controlled chemical composition. The development of efficient nanocatalysts supposes the characterization of their various surface active sites at the nanometer scale, which is focused on establishing synthesis–structure–performance relationships. 2021-05-01T15:44:08Z 2021-05-01T15:44:08Z 2020 book ONIX_20210501_9783039432509_970 9783039432509 9783039432516 https://directory.doabooks.org/handle/20.500.12854/69224 eng application/octet-stream Attribution 4.0 International https://mdpi.com/books/pdfview/book/2997 https://mdpi.com/books/pdfview/book/2997 MDPI - Multidisciplinary Digital Publishing Institute 10.3390/books978-3-03943-251-6 10.3390/books978-3-03943-251-6 46cabcaa-dd94-4bfe-87b4-55023c1b36d0 9783039432509 9783039432516 190 Basel, Switzerland open access
spellingShingle plasmonic photocatalyst
metal nanoparticle
N–TiO2
nanocomposites
photocatalytic selective oxidation
heterogeneous catalysis
transition metal nitrides
hydrogen production
formic acid decomposition
nickel catalyst
calcium oxide promoter
silica support
Iron-based perovskites
copper
NO oxidation to NO2
NO2-assisted diesel soot oxidation
soot oxidation under GDI exhaust conditions
aqueous-phase reforming
nickel
ceria
zirconia
calcium
yttrium
methanol
graphite
reduced graphene oxide
nitrogen-doped reduced graphene oxide
exfoliation
oxygen reduction reaction
electrocatalysis
UiO-66
iron
cobalt
nanocatalyst
CO oxidation
COProx
methane
oxidation catalysis
formaldehyde
magnetite iron oxide
Fe3O4
palladium
Pd
silver
Ag
low-temperature activity
nanocomposite
Raman
TG in air
TG in hydrogen
XRD
electron microscopy
EDS
coordination polymers
methane storage
XRD crystallinity measurements
mechanical shaping
compaction
VAM
gas separation
MOF pelletization
catalysts
dimerization
isobutene
olefins
n/a
thema EDItEUR::G Reference, Information and Interdisciplinary subjects::GP Research and information: general
Application of New Nanoparticle Structures as Catalysts
title Application of New Nanoparticle Structures as Catalysts
title_full Application of New Nanoparticle Structures as Catalysts
title_fullStr Application of New Nanoparticle Structures as Catalysts
title_full_unstemmed Application of New Nanoparticle Structures as Catalysts
title_short Application of New Nanoparticle Structures as Catalysts
title_sort application of new nanoparticle structures as catalysts
topic plasmonic photocatalyst
metal nanoparticle
N–TiO2
nanocomposites
photocatalytic selective oxidation
heterogeneous catalysis
transition metal nitrides
hydrogen production
formic acid decomposition
nickel catalyst
calcium oxide promoter
silica support
Iron-based perovskites
copper
NO oxidation to NO2
NO2-assisted diesel soot oxidation
soot oxidation under GDI exhaust conditions
aqueous-phase reforming
nickel
ceria
zirconia
calcium
yttrium
methanol
graphite
reduced graphene oxide
nitrogen-doped reduced graphene oxide
exfoliation
oxygen reduction reaction
electrocatalysis
UiO-66
iron
cobalt
nanocatalyst
CO oxidation
COProx
methane
oxidation catalysis
formaldehyde
magnetite iron oxide
Fe3O4
palladium
Pd
silver
Ag
low-temperature activity
nanocomposite
Raman
TG in air
TG in hydrogen
XRD
electron microscopy
EDS
coordination polymers
methane storage
XRD crystallinity measurements
mechanical shaping
compaction
VAM
gas separation
MOF pelletization
catalysts
dimerization
isobutene
olefins
n/a
thema EDItEUR::G Reference, Information and Interdisciplinary subjects::GP Research and information: general
topic_facet plasmonic photocatalyst
metal nanoparticle
N–TiO2
nanocomposites
photocatalytic selective oxidation
heterogeneous catalysis
transition metal nitrides
hydrogen production
formic acid decomposition
nickel catalyst
calcium oxide promoter
silica support
Iron-based perovskites
copper
NO oxidation to NO2
NO2-assisted diesel soot oxidation
soot oxidation under GDI exhaust conditions
aqueous-phase reforming
nickel
ceria
zirconia
calcium
yttrium
methanol
graphite
reduced graphene oxide
nitrogen-doped reduced graphene oxide
exfoliation
oxygen reduction reaction
electrocatalysis
UiO-66
iron
cobalt
nanocatalyst
CO oxidation
COProx
methane
oxidation catalysis
formaldehyde
magnetite iron oxide
Fe3O4
palladium
Pd
silver
Ag
low-temperature activity
nanocomposite
Raman
TG in air
TG in hydrogen
XRD
electron microscopy
EDS
coordination polymers
methane storage
XRD crystallinity measurements
mechanical shaping
compaction
VAM
gas separation
MOF pelletization
catalysts
dimerization
isobutene
olefins
n/a
thema EDItEUR::G Reference, Information and Interdisciplinary subjects::GP Research and information: general
url ONIX_20210501_9783039432509_970