Carbon Ligands

Homogeneous catalysis owes its success, in large part, to the development of a wide range of ligands with well-defined electronic and steric properties, which have thus made it possible to adjust the behavior of many organometallic complexes. However, ligands used in catalysis have long been centere...

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Хэвлэсэн: MDPI - Multidisciplinary Digital Publishing Institute 2022
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Онлайн хандалт:ONIX_20220111_9783036513508_194
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collection Directory of Open Access Books
description Homogeneous catalysis owes its success, in large part, to the development of a wide range of ligands with well-defined electronic and steric properties, which have thus made it possible to adjust the behavior of many organometallic complexes. However, ligands used in catalysis have long been centered on elements of group 15, and it is only more recently that carbon ligands have proved to be valuable alternatives with the emergence of cyclic diaminocarbenes (NHC).This Special Issue aims to provide a contemporary overview of the advances in carbon ligand chemistry from fundamental aspects to applications.
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institution Directory of Open Access Books
language eng
publishDate 2022
publishDateRange 2022
publishDateSort 2022
publisher MDPI - Multidisciplinary Digital Publishing Institute
publisherStr MDPI - Multidisciplinary Digital Publishing Institute
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spelling doab-20.500.12854ir-764582024-03-27T16:34:21Z Carbon Ligands Canac, Yves carbenes ylides DFT calculations electronic structure catalysis ligands structure–activity relationship NHC nanoparticle calixarene palladium catalyst Suzuki-Miyaura reaction amino-acids water carbon ligand amide negative charge phosphonium ylide oxide pincer metathesis ruthenium nitro catalysts NHC ligands olefins selenonium ylides selenonium salts chirality stereogenic selenium atom asymmetric synthesis optical resolution reactivity malaria Plasmodium falciparum gold NHC-ligands hybrid molecules drug resistance N-heterocyclic carbene platinum metal complexes 195Pt NMR N-heterocyclic carbenes imidazole spectroscopy X-ray mercury(II) complex T-shaped carbodiphosphorane phosphorus ylides pincer ligands coordination chemistry Cu(I) complex photoluminescence titanium hafnium copolymerization of epoxide with CO2 density functional theory natural bond orbitals aromaticity ion pairs alkali metals tropylidenyl ions cyclooctatetraene ions rhodium electron paramagnetic resonance (EPR) spectroscopy density functional theory (DFT) electrochemistry carbone complexes carbido complexes transition metal complexes chemical bonding pincer ligand macrocycle lithium potassium intramolecular C-H activation dehydrogenation carbone ligand germylene coordination ylide n/a thema EDItEUR::G Reference, Information and Interdisciplinary subjects::GP Research and information: general Homogeneous catalysis owes its success, in large part, to the development of a wide range of ligands with well-defined electronic and steric properties, which have thus made it possible to adjust the behavior of many organometallic complexes. However, ligands used in catalysis have long been centered on elements of group 15, and it is only more recently that carbon ligands have proved to be valuable alternatives with the emergence of cyclic diaminocarbenes (NHC).This Special Issue aims to provide a contemporary overview of the advances in carbon ligand chemistry from fundamental aspects to applications. 2022-01-11T13:32:30Z 2022-01-11T13:32:30Z 2021 book ONIX_20220111_9783036513508_194 9783036513508 9783036513492 https://directory.doabooks.org/handle/20.500.12854/76458 eng image/jpeg Attribution 4.0 International https://mdpi.com/books/pdfview/book/3894 https://mdpi.com/books/pdfview/book/3894 MDPI - Multidisciplinary Digital Publishing Institute 10.3390/books978-3-0365-1349-2 10.3390/books978-3-0365-1349-2 46cabcaa-dd94-4bfe-87b4-55023c1b36d0 9783036513508 9783036513492 311 Basel, Switzerland open access
spellingShingle carbenes
ylides
DFT calculations
electronic structure
catalysis
ligands
structure–activity relationship
NHC
nanoparticle
calixarene
palladium catalyst
Suzuki-Miyaura reaction
amino-acids
water
carbon ligand
amide
negative charge
phosphonium ylide
oxide
pincer
metathesis
ruthenium
nitro catalysts
NHC ligands
olefins
selenonium ylides
selenonium salts
chirality
stereogenic selenium atom
asymmetric synthesis
optical resolution
reactivity
malaria
Plasmodium falciparum
gold
NHC-ligands
hybrid molecules
drug resistance
N-heterocyclic carbene
platinum
metal complexes
195Pt NMR
N-heterocyclic carbenes
imidazole
spectroscopy
X-ray
mercury(II) complex
T-shaped
carbodiphosphorane
phosphorus ylides
pincer ligands
coordination chemistry
Cu(I) complex
photoluminescence
titanium
hafnium
copolymerization of epoxide with CO2
density functional theory
natural bond orbitals
aromaticity
ion pairs
alkali metals
tropylidenyl ions
cyclooctatetraene ions
rhodium
electron paramagnetic resonance (EPR) spectroscopy
density functional theory (DFT)
electrochemistry
carbone complexes
carbido complexes
transition metal complexes
chemical bonding
pincer ligand
macrocycle
lithium
potassium
intramolecular C-H activation
dehydrogenation
carbone
ligand
germylene
coordination
ylide
n/a
thema EDItEUR::G Reference, Information and Interdisciplinary subjects::GP Research and information: general
Carbon Ligands
title Carbon Ligands
title_full Carbon Ligands
title_fullStr Carbon Ligands
title_full_unstemmed Carbon Ligands
title_short Carbon Ligands
title_sort carbon ligands
topic carbenes
ylides
DFT calculations
electronic structure
catalysis
ligands
structure–activity relationship
NHC
nanoparticle
calixarene
palladium catalyst
Suzuki-Miyaura reaction
amino-acids
water
carbon ligand
amide
negative charge
phosphonium ylide
oxide
pincer
metathesis
ruthenium
nitro catalysts
NHC ligands
olefins
selenonium ylides
selenonium salts
chirality
stereogenic selenium atom
asymmetric synthesis
optical resolution
reactivity
malaria
Plasmodium falciparum
gold
NHC-ligands
hybrid molecules
drug resistance
N-heterocyclic carbene
platinum
metal complexes
195Pt NMR
N-heterocyclic carbenes
imidazole
spectroscopy
X-ray
mercury(II) complex
T-shaped
carbodiphosphorane
phosphorus ylides
pincer ligands
coordination chemistry
Cu(I) complex
photoluminescence
titanium
hafnium
copolymerization of epoxide with CO2
density functional theory
natural bond orbitals
aromaticity
ion pairs
alkali metals
tropylidenyl ions
cyclooctatetraene ions
rhodium
electron paramagnetic resonance (EPR) spectroscopy
density functional theory (DFT)
electrochemistry
carbone complexes
carbido complexes
transition metal complexes
chemical bonding
pincer ligand
macrocycle
lithium
potassium
intramolecular C-H activation
dehydrogenation
carbone
ligand
germylene
coordination
ylide
n/a
thema EDItEUR::G Reference, Information and Interdisciplinary subjects::GP Research and information: general
topic_facet carbenes
ylides
DFT calculations
electronic structure
catalysis
ligands
structure–activity relationship
NHC
nanoparticle
calixarene
palladium catalyst
Suzuki-Miyaura reaction
amino-acids
water
carbon ligand
amide
negative charge
phosphonium ylide
oxide
pincer
metathesis
ruthenium
nitro catalysts
NHC ligands
olefins
selenonium ylides
selenonium salts
chirality
stereogenic selenium atom
asymmetric synthesis
optical resolution
reactivity
malaria
Plasmodium falciparum
gold
NHC-ligands
hybrid molecules
drug resistance
N-heterocyclic carbene
platinum
metal complexes
195Pt NMR
N-heterocyclic carbenes
imidazole
spectroscopy
X-ray
mercury(II) complex
T-shaped
carbodiphosphorane
phosphorus ylides
pincer ligands
coordination chemistry
Cu(I) complex
photoluminescence
titanium
hafnium
copolymerization of epoxide with CO2
density functional theory
natural bond orbitals
aromaticity
ion pairs
alkali metals
tropylidenyl ions
cyclooctatetraene ions
rhodium
electron paramagnetic resonance (EPR) spectroscopy
density functional theory (DFT)
electrochemistry
carbone complexes
carbido complexes
transition metal complexes
chemical bonding
pincer ligand
macrocycle
lithium
potassium
intramolecular C-H activation
dehydrogenation
carbone
ligand
germylene
coordination
ylide
n/a
thema EDItEUR::G Reference, Information and Interdisciplinary subjects::GP Research and information: general
url ONIX_20220111_9783036513508_194