Transition Metal Catalyzed Cross-Coupling Reactions
Transition metal-catalyzed cross-coupling reactions have proved to be powerful tools for carbon–carbon as well as carbon–heteroatom bond formation in the development of synthetic methodologies for applications ranging from pharmaceuticals to materials. This book, consisting of an editorial, two revi...
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| Materiálatiipa: | Online |
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| Giella: | eaŋgalasgiella |
| Almmustuhtton: |
MDPI - Multidisciplinary Digital Publishing Institute
2022
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| Fáttát: | |
| Liŋkkat: | ONIX_20220111_9783036525778_927 |
| Fáddágilkorat: |
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| _version_ | 1869527209303080960 |
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| collection | Directory of Open Access Books |
| description | Transition metal-catalyzed cross-coupling reactions have proved to be powerful tools for carbon–carbon as well as carbon–heteroatom bond formation in the development of synthetic methodologies for applications ranging from pharmaceuticals to materials. This book, consisting of an editorial, two reviews and two articles, focuses on recent promising research and novel trends in the field of cross-coupling reactions, employing a range of different catalysts. A review by Kostas and Steele provides a survey of the research in the area of cross-coupling catalytic reactions with transition metal complexes based on the thiosemicarbazone unit and a discussion of the prospects for future developments. Another review by Polychronopoulou, Shaya and co-authors describes the progress made over the 21st century concerning the utilization of C(sp3)–organoboranes as partners in metal-catalyzed C(sp3)–C(sp2) cross-couplings, such as B-alkyl Suzuki–Miyaura reactions. The article by Waldvogel, Breinbauer and co-authors demonstrates for the first time the synthetic potential of combining the electro-oxidative dehydrogenative cross coupling of ortho-substituted phenols with Pd-catalyzed cross-coupling reactions. In the second article, Štĕpnička and co-workers describe the preparation of palladium catalysts deposited over silica gel-bearing composite amide-donor functional moieties on the surface, which were evaluated in the Sonogashira-type cross-coupling of acyl chlorides with terminal alkynes. |
| format | Online |
| id | doab-20.500.12854ir-77095 |
| institution | Directory of Open Access Books |
| language | eng |
| publishDate | 2022 |
| publishDateRange | 2022 |
| publishDateSort | 2022 |
| publisher | MDPI - Multidisciplinary Digital Publishing Institute |
| publisherStr | MDPI - Multidisciplinary Digital Publishing Institute |
| record_format | ojs |
| spelling | doab-20.500.12854ir-770952024-04-09T23:15:37Z Transition Metal Catalyzed Cross-Coupling Reactions Kostas, Ioannis Suzuki–Miyaura cross-couplings C(sp3) –C(sp2) alkylboron reagents metal catalysis alpha-helix anode CH-activation cross-coupling electrosynthesis oligoarene peptidomimetics phenol protein-protein interactions triflate thiosemicarbazone metal complex transition metal catalysis cross-coupling reaction Heck reaction Suzuki reaction Sonogashira reaction Kumada reaction Buchwald–Hartwig reaction deposited catalysts palladium functional amides alkynyl ketone synthesis n/a thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TB Technology: general issues Transition metal-catalyzed cross-coupling reactions have proved to be powerful tools for carbon–carbon as well as carbon–heteroatom bond formation in the development of synthetic methodologies for applications ranging from pharmaceuticals to materials. This book, consisting of an editorial, two reviews and two articles, focuses on recent promising research and novel trends in the field of cross-coupling reactions, employing a range of different catalysts. A review by Kostas and Steele provides a survey of the research in the area of cross-coupling catalytic reactions with transition metal complexes based on the thiosemicarbazone unit and a discussion of the prospects for future developments. Another review by Polychronopoulou, Shaya and co-authors describes the progress made over the 21st century concerning the utilization of C(sp3)–organoboranes as partners in metal-catalyzed C(sp3)–C(sp2) cross-couplings, such as B-alkyl Suzuki–Miyaura reactions. The article by Waldvogel, Breinbauer and co-authors demonstrates for the first time the synthetic potential of combining the electro-oxidative dehydrogenative cross coupling of ortho-substituted phenols with Pd-catalyzed cross-coupling reactions. In the second article, Štĕpnička and co-workers describe the preparation of palladium catalysts deposited over silica gel-bearing composite amide-donor functional moieties on the surface, which were evaluated in the Sonogashira-type cross-coupling of acyl chlorides with terminal alkynes. 2022-01-11T13:52:00Z 2022-01-11T13:52:00Z 2021 book ONIX_20220111_9783036525778_927 9783036525778 9783036525761 https://directory.doabooks.org/handle/20.500.12854/77095 eng image/jpeg Attribution 4.0 International https://mdpi.com/books/pdfview/book/4714 https://mdpi.com/books/pdfview/book/4714 MDPI - Multidisciplinary Digital Publishing Institute 10.3390/books978-3-0365-2576-1 10.3390/books978-3-0365-2576-1 46cabcaa-dd94-4bfe-87b4-55023c1b36d0 9783036525778 9783036525761 88 Basel, Switzerland open access |
| spellingShingle | Suzuki–Miyaura cross-couplings C(sp3) –C(sp2) alkylboron reagents metal catalysis alpha-helix anode CH-activation cross-coupling electrosynthesis oligoarene peptidomimetics phenol protein-protein interactions triflate thiosemicarbazone metal complex transition metal catalysis cross-coupling reaction Heck reaction Suzuki reaction Sonogashira reaction Kumada reaction Buchwald–Hartwig reaction deposited catalysts palladium functional amides alkynyl ketone synthesis n/a thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TB Technology: general issues Transition Metal Catalyzed Cross-Coupling Reactions |
| title | Transition Metal Catalyzed Cross-Coupling Reactions |
| title_full | Transition Metal Catalyzed Cross-Coupling Reactions |
| title_fullStr | Transition Metal Catalyzed Cross-Coupling Reactions |
| title_full_unstemmed | Transition Metal Catalyzed Cross-Coupling Reactions |
| title_short | Transition Metal Catalyzed Cross-Coupling Reactions |
| title_sort | transition metal catalyzed cross coupling reactions |
| topic | Suzuki–Miyaura cross-couplings C(sp3) –C(sp2) alkylboron reagents metal catalysis alpha-helix anode CH-activation cross-coupling electrosynthesis oligoarene peptidomimetics phenol protein-protein interactions triflate thiosemicarbazone metal complex transition metal catalysis cross-coupling reaction Heck reaction Suzuki reaction Sonogashira reaction Kumada reaction Buchwald–Hartwig reaction deposited catalysts palladium functional amides alkynyl ketone synthesis n/a thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TB Technology: general issues |
| topic_facet | Suzuki–Miyaura cross-couplings C(sp3) –C(sp2) alkylboron reagents metal catalysis alpha-helix anode CH-activation cross-coupling electrosynthesis oligoarene peptidomimetics phenol protein-protein interactions triflate thiosemicarbazone metal complex transition metal catalysis cross-coupling reaction Heck reaction Suzuki reaction Sonogashira reaction Kumada reaction Buchwald–Hartwig reaction deposited catalysts palladium functional amides alkynyl ketone synthesis n/a thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TB Technology: general issues |
| url | ONIX_20220111_9783036525778_927 |