Catalysts and Processes for H2S Conversion to Sulfur

Today, more stringent regulations on SOx emissions and growing environmental concerns have led to considerable attention on sulfur recovery from hydrogen sulfide (H2S). Hydrogen sulfide is commonly found in raw natural gas and biogas, even if a great amount is obtained through sweetening of sour nat...

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اللغة:الإنجليزية
منشور في: MDPI - Multidisciplinary Digital Publishing Institute 2022
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collection Directory of Open Access Books
description Today, more stringent regulations on SOx emissions and growing environmental concerns have led to considerable attention on sulfur recovery from hydrogen sulfide (H2S). Hydrogen sulfide is commonly found in raw natural gas and biogas, even if a great amount is obtained through sweetening of sour natural gas and hydrodesulphurization of light hydrocarbons. It is highly toxic, extremely corrosive and flammable, and for these reasons, its elimination is necessary prior to emission in atmosphere. There are different technologies for the removal of H2S, the drawbacks of which are the high costs and limited H2S conversion efficiency. The main focus of this Special Issue will be on catalytic oxidation processes, but the issue is devoted to the development of catalysts able to maximize H2S conversion to sulfur minimizing SO2 formation, pursuing the goal of “zero SO2 emission”.This Special Issue is particularly devoted to the preparation of novel powdered/structured supported catalysts and their physical–chemical characterization, the study of the aspects concerning stability and reusability, as well as the phenomena that could underlie the deactivation of the catalyst.This Special Issue comprises seven articles, one communication, and one review regarding the desulfurization of sour gases and fuel oil, as well as the synthesis of novel adsorbents and catalysts for H2S abatement. In the following, a brief description of the papers included in this issue is provided to serve as an outline to encourage further reading.
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spelling doab-20.500.12854ir-795692024-03-28T03:31:38Z Catalysts and Processes for H2S Conversion to Sulfur Barba, Daniela hydrogen sulfide biocoal livestock manure agricultural safety fertilizer waste management air pollution odor kinetics Gompertz model phosphine manganese slag metal ions reaction mechanism mesoporous N-doped carbon coating silicon carbide composites gas-tail desulfurization treatment BTX contaminants elemental sulfur chicken eggshell waste valorization adsorption biogas flue gas polyoxometalate dicationic ionic liquids extraction oxidative desulfurization dibenzothiophene adsorbent purification H2S removal response surface methodology (RSM) H2S selective partial oxidation sulfur sulfur dioxide vanadium-based catalysts hydrochar mixed metal oxides H2S conversion n/a gas purification direct catalytic oxidation fluidized catalyst bed hydrogen sulfide removal facilities thema EDItEUR::G Reference, Information and Interdisciplinary subjects::GP Research and information: general thema EDItEUR::K Economics, Finance, Business and Management::KC Economics::KCV Economics of specific sectors::KCVG Environmental economics thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TQ Environmental science, engineering and technology::TQK Pollution control Today, more stringent regulations on SOx emissions and growing environmental concerns have led to considerable attention on sulfur recovery from hydrogen sulfide (H2S). Hydrogen sulfide is commonly found in raw natural gas and biogas, even if a great amount is obtained through sweetening of sour natural gas and hydrodesulphurization of light hydrocarbons. It is highly toxic, extremely corrosive and flammable, and for these reasons, its elimination is necessary prior to emission in atmosphere. There are different technologies for the removal of H2S, the drawbacks of which are the high costs and limited H2S conversion efficiency. The main focus of this Special Issue will be on catalytic oxidation processes, but the issue is devoted to the development of catalysts able to maximize H2S conversion to sulfur minimizing SO2 formation, pursuing the goal of “zero SO2 emission”.This Special Issue is particularly devoted to the preparation of novel powdered/structured supported catalysts and their physical–chemical characterization, the study of the aspects concerning stability and reusability, as well as the phenomena that could underlie the deactivation of the catalyst.This Special Issue comprises seven articles, one communication, and one review regarding the desulfurization of sour gases and fuel oil, as well as the synthesis of novel adsorbents and catalysts for H2S abatement. In the following, a brief description of the papers included in this issue is provided to serve as an outline to encourage further reading. 2022-03-21T16:26:32Z 2022-03-21T16:26:32Z 2022 book ONIX_20220321_9783036531373_5 9783036531373 9783036531366 https://directory.doabooks.org/handle/20.500.12854/79569 eng image/jpeg Attribution 4.0 International https://mdpi.com/books/pdfview/book/4949 https://mdpi.com/books/pdfview/book/4949 MDPI - Multidisciplinary Digital Publishing Institute 10.3390/books978-3-0365-3136-6 10.3390/books978-3-0365-3136-6 46cabcaa-dd94-4bfe-87b4-55023c1b36d0 9783036531373 9783036531366 206 Basel open access
spellingShingle hydrogen sulfide
biocoal
livestock manure
agricultural safety
fertilizer
waste management
air pollution
odor
kinetics
Gompertz model
phosphine
manganese slag
metal ions
reaction mechanism
mesoporous N-doped carbon coating
silicon carbide composites
gas-tail desulfurization treatment
BTX contaminants
elemental sulfur
chicken eggshell
waste valorization
adsorption
biogas
flue gas
polyoxometalate
dicationic ionic liquids
extraction
oxidative desulfurization
dibenzothiophene
adsorbent
purification
H2S removal
response surface methodology (RSM)
H2S selective partial oxidation
sulfur
sulfur dioxide
vanadium-based catalysts
hydrochar
mixed metal oxides
H2S conversion
n/a
gas purification
direct catalytic oxidation
fluidized catalyst bed
hydrogen sulfide removal facilities
thema EDItEUR::G Reference, Information and Interdisciplinary subjects::GP Research and information: general
thema EDItEUR::K Economics, Finance, Business and Management::KC Economics::KCV Economics of specific sectors::KCVG Environmental economics
thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TQ Environmental science, engineering and technology::TQK Pollution control
Catalysts and Processes for H2S Conversion to Sulfur
title Catalysts and Processes for H2S Conversion to Sulfur
title_full Catalysts and Processes for H2S Conversion to Sulfur
title_fullStr Catalysts and Processes for H2S Conversion to Sulfur
title_full_unstemmed Catalysts and Processes for H2S Conversion to Sulfur
title_short Catalysts and Processes for H2S Conversion to Sulfur
title_sort catalysts and processes for h2s conversion to sulfur
topic hydrogen sulfide
biocoal
livestock manure
agricultural safety
fertilizer
waste management
air pollution
odor
kinetics
Gompertz model
phosphine
manganese slag
metal ions
reaction mechanism
mesoporous N-doped carbon coating
silicon carbide composites
gas-tail desulfurization treatment
BTX contaminants
elemental sulfur
chicken eggshell
waste valorization
adsorption
biogas
flue gas
polyoxometalate
dicationic ionic liquids
extraction
oxidative desulfurization
dibenzothiophene
adsorbent
purification
H2S removal
response surface methodology (RSM)
H2S selective partial oxidation
sulfur
sulfur dioxide
vanadium-based catalysts
hydrochar
mixed metal oxides
H2S conversion
n/a
gas purification
direct catalytic oxidation
fluidized catalyst bed
hydrogen sulfide removal facilities
thema EDItEUR::G Reference, Information and Interdisciplinary subjects::GP Research and information: general
thema EDItEUR::K Economics, Finance, Business and Management::KC Economics::KCV Economics of specific sectors::KCVG Environmental economics
thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TQ Environmental science, engineering and technology::TQK Pollution control
topic_facet hydrogen sulfide
biocoal
livestock manure
agricultural safety
fertilizer
waste management
air pollution
odor
kinetics
Gompertz model
phosphine
manganese slag
metal ions
reaction mechanism
mesoporous N-doped carbon coating
silicon carbide composites
gas-tail desulfurization treatment
BTX contaminants
elemental sulfur
chicken eggshell
waste valorization
adsorption
biogas
flue gas
polyoxometalate
dicationic ionic liquids
extraction
oxidative desulfurization
dibenzothiophene
adsorbent
purification
H2S removal
response surface methodology (RSM)
H2S selective partial oxidation
sulfur
sulfur dioxide
vanadium-based catalysts
hydrochar
mixed metal oxides
H2S conversion
n/a
gas purification
direct catalytic oxidation
fluidized catalyst bed
hydrogen sulfide removal facilities
thema EDItEUR::G Reference, Information and Interdisciplinary subjects::GP Research and information: general
thema EDItEUR::K Economics, Finance, Business and Management::KC Economics::KCV Economics of specific sectors::KCVG Environmental economics
thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TQ Environmental science, engineering and technology::TQK Pollution control
url ONIX_20220321_9783036531373_5