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Carborane: Dedicated to the Work of Professor Alan Welch

This Special Issue on carboranes is dedicated to Prof. Alan Welch on the occasion of his retirement and his outstanding contributions to the field of carborane chemistry. Polyhedral carboranes lie at the interface of organic and inorganic chemistry. One of their most attractive and important featur...

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Gespeichert in:
Format: Online
Sprache:Englisch
Veröffentlicht: MDPI - Multidisciplinary Digital Publishing Institute 2022
Schlagworte:
carboranes
DFT
reaction pathways
boron chemistry
o-carborane
sulfa-Michael addition reaction
cysteine
boron neutron capture therapy
o-carborane decapitation
labeled compound
1,1′-bis(o-carborane)
deboronation
metalation
bis(nickelation)
diastereoisomers
stereospecific
boron clusters
liquid crystals
fluorescence
cholesterol
nido-carborane
nitrilium derivatives
nickel(II) half-sandwich complexes
synthesis
structure
Lewis acid
carborane
carbonium ylide
tetrel bond
quantum chemistry
electron density
ELF
iodo derivatives
dihalogen bond
X-ray structure
quantum chemical calculations
iron bis(1,2-dicarbollide)
chromium bis(1,2-dicarbollide)
tetramethyltetrathiafulvalene
tetramethyltetraselenafulvalene
radical-cation salts
crystal and molecular structure
electric conductivity
n/a
thema EDItEUR::G Reference, Information and Interdisciplinary subjects::GP Research and information: general
Online-Zugang:ONIX_20220506_9783036536194_276
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Zusammenfassung:This Special Issue on carboranes is dedicated to Prof. Alan Welch on the occasion of his retirement and his outstanding contributions to the field of carborane chemistry. Polyhedral carboranes lie at the interface of organic and inorganic chemistry. One of their most attractive and important features is the variety and beauty of their chemical structures. They have found applications as diverse as catalysis, in Boron Neutron Capture Therapy, as liquid crystals and as semiconductors. This Special Issue illustrates the very comprehensive world of heteroborane chemistry, from liquid crystals to BNCT agents, di-halogen bonding to quantum chemical calculations of tetrel complexes of the carbonium ylide CB11H11, nickellacarboranes as potential acid–base sensors to revealing how the selective formations of metallacarborane diastereomers can arise and metallacarboranes as function as radical cation salts with dielectric or semiconductor properties.

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