Heterobimetallic [2.2]Paracyclophane Complexes and Their Application in Photoredox Catalysis
The most important goal of current chemistry research is to provide green and sustainable routes to compounds of interest. One way of addressing this is the use of abundant and inexpensive sources of energy to drive reactions, with the prime example being visible light in photoredox catalysis. One r...
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| Format: | Online |
| Język: | angielski |
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Logos Verlag Berlin
2022
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| Dostęp online: | OCN: 1266753357 |
| Etykiety: |
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| _version_ | 1869515233479884800 |
|---|---|
| author | Knoll, Daniel |
| author_browse | Knoll, Daniel |
| author_facet | Knoll, Daniel |
| author_sort | Knoll, Daniel |
| collection | Directory of Open Access Books |
| description | The most important goal of current chemistry research is to provide green and sustainable routes to compounds of interest. One way of addressing this is the use of abundant and inexpensive sources of energy to drive reactions, with the prime example being visible light in photoredox catalysis. One recent promising approach is the use of heterobimetallic catalysts where two metals work in a cooperative fashion to achieve the desired transformation. However, these cooperative effects are poorly understood due to a lack of model complexes suitable for the intricate study of heterobimetallic complexes.
In this work, [2.2]paracyclophane (PCP) is presented as a new platform on which to build distance-variable heterobimetallic complexes. The methods for the access to these synthetic targets are developed and investigated for their broader synthetic applicability.
To demonstrate the potential of these complexes as catalysts, Au/Ru heterobimetallic complexes are evaluated regarding their performance in a dual photoredox catalytic arylative Meyer-Schuster rearrangement reaction. This reaction provides a very convenient and sustainable access α-arylated enones, an important building blocks for relevant pharmaceutical compounds. |
| format | Online |
| id | doab-20.500.12854ir-84254 |
| institution | Directory of Open Access Books |
| language | eng |
| publishDate | 2022 |
| publishDateRange | 2022 |
| publishDateSort | 2022 |
| publisher | Logos Verlag Berlin |
| publisherStr | Logos Verlag Berlin |
| record_format | ojs |
| spelling | doab-20.500.12854ir-842542025-07-30T18:29:03Z Heterobimetallic [2.2]Paracyclophane Complexes and Their Application in Photoredox Catalysis Knoll, Daniel The most important goal of current chemistry research is to provide green and sustainable routes to compounds of interest. One way of addressing this is the use of abundant and inexpensive sources of energy to drive reactions, with the prime example being visible light in photoredox catalysis. One recent promising approach is the use of heterobimetallic catalysts where two metals work in a cooperative fashion to achieve the desired transformation. However, these cooperative effects are poorly understood due to a lack of model complexes suitable for the intricate study of heterobimetallic complexes. In this work, [2.2]paracyclophane (PCP) is presented as a new platform on which to build distance-variable heterobimetallic complexes. The methods for the access to these synthetic targets are developed and investigated for their broader synthetic applicability. To demonstrate the potential of these complexes as catalysts, Au/Ru heterobimetallic complexes are evaluated regarding their performance in a dual photoredox catalytic arylative Meyer-Schuster rearrangement reaction. This reaction provides a very convenient and sustainable access α-arylated enones, an important building blocks for relevant pharmaceutical compounds. 2022-06-19T04:03:31Z 2022-06-19T04:03:31Z 2022-06-18T05:36:15Z 2020 book OCN: 1266753357 https://library.oapen.org/handle/20.500.12657/56771 9783832550714 https://directory.doabooks.org/handle/20.500.12854/84254 eng open access image/jpeg image/jpeg image/jpeg image/jpeg n/a n/a n/a n/a https://library.oapen.org/bitstream/20.500.12657/56771/1/external_content.pdf https://library.oapen.org/bitstream/20.500.12657/56771/1/external_content.pdf https://library.oapen.org/bitstream/20.500.12657/56771/1/external_content.pdf https://library.oapen.org/bitstream/20.500.12657/56771/1/external_content.pdf Logos Verlag Berlin Logos Verlag Berlin https://doi.org/10.30819/5071 https://doi.org/10.30819/5071 04b263a1-7fba-4491-9eae-1c394ac42fc3 Knowledge Unlatched 9783832550714 Knowledge Unlatched (KU) KU Open Services Logos Verlag Berlin open access |
| spellingShingle | Knoll, Daniel Heterobimetallic [2.2]Paracyclophane Complexes and Their Application in Photoredox Catalysis |
| title | Heterobimetallic [2.2]Paracyclophane Complexes and Their Application in Photoredox Catalysis |
| title_full | Heterobimetallic [2.2]Paracyclophane Complexes and Their Application in Photoredox Catalysis |
| title_fullStr | Heterobimetallic [2.2]Paracyclophane Complexes and Their Application in Photoredox Catalysis |
| title_full_unstemmed | Heterobimetallic [2.2]Paracyclophane Complexes and Their Application in Photoredox Catalysis |
| title_short | Heterobimetallic [2.2]Paracyclophane Complexes and Their Application in Photoredox Catalysis |
| title_sort | heterobimetallic 2 2 paracyclophane complexes and their application in photoredox catalysis |
| url | OCN: 1266753357 |
| work_keys_str_mv | AT knolldaniel heterobimetallic22paracyclophanecomplexesandtheirapplicationinphotoredoxcatalysis |