Covalent Organic Frameworks
In recent decades, artificial porous structures have attracted increasing enthusiasm from researchers inspired by the fascinating molecular pores in nature and their unique biological functions. Although substantial achievements in porous materials have been realized, the construction of topological...
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| Formaat: | Online |
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| Taal: | Engels |
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IntechOpen
2023
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| Online toegang: | ONIX_20230215_9781803569604_373 |
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| _version_ | 1869517698862415872 |
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| collection | Directory of Open Access Books |
| description | In recent decades, artificial porous structures have attracted increasing enthusiasm from researchers inspired by the fascinating molecular pores in nature and their unique biological functions. Although substantial achievements in porous materials have been realized, the construction of topologically designed pores is still challenging. Recently, the emergence of covalent organic frameworks (COFs), which are constructed based on organic and polymer chemistry, has made it possible to design artificial pores with controlled pore size, topology and interface properties. COFs are crystalline porous materials constructed by the precise reticulation of organic building blocks via dynamic covalent bonds. Distinct from non-covalent interactions which tend to produce isostructures, covalent bonds enable accurate pore design owing to their predetermined reaction pathways. In addition, the appropriate polycondensation of organic building units enables the formation of extended two-dimensional (2D) and three-dimensional (3D) polymer architectures with periodically ordered skeletons and well-defined pores. With their large surface area, tailorable structures, and tunable chemistry, COFs are regarded as potentially superior candidates for various applications including catalysis, energy storage and conversion, mass transport and biotechnology. This book examines the historic achievement of COFs, providing clear and comprehensive guidance for researchers on their structural design, synthetic protocols and functional exploration. |
| format | Online |
| id | doab-20.500.12854ir-97335 |
| institution | Directory of Open Access Books |
| language | eng |
| publishDate | 2023 |
| publishDateRange | 2023 |
| publishDateSort | 2023 |
| publisher | IntechOpen |
| publisherStr | IntechOpen |
| record_format | ojs |
| spelling | doab-20.500.12854ir-973352024-04-05T12:41:08Z Covalent Organic Frameworks Gao, Yanan Lu, Fei Chemistry thema EDItEUR::P Mathematics and Science::PN Chemistry::PNN Organic chemistry In recent decades, artificial porous structures have attracted increasing enthusiasm from researchers inspired by the fascinating molecular pores in nature and their unique biological functions. Although substantial achievements in porous materials have been realized, the construction of topologically designed pores is still challenging. Recently, the emergence of covalent organic frameworks (COFs), which are constructed based on organic and polymer chemistry, has made it possible to design artificial pores with controlled pore size, topology and interface properties. COFs are crystalline porous materials constructed by the precise reticulation of organic building blocks via dynamic covalent bonds. Distinct from non-covalent interactions which tend to produce isostructures, covalent bonds enable accurate pore design owing to their predetermined reaction pathways. In addition, the appropriate polycondensation of organic building units enables the formation of extended two-dimensional (2D) and three-dimensional (3D) polymer architectures with periodically ordered skeletons and well-defined pores. With their large surface area, tailorable structures, and tunable chemistry, COFs are regarded as potentially superior candidates for various applications including catalysis, energy storage and conversion, mass transport and biotechnology. This book examines the historic achievement of COFs, providing clear and comprehensive guidance for researchers on their structural design, synthetic protocols and functional exploration. 2023-02-15T14:58:32Z 2023-02-15T14:58:32Z 2023 book ONIX_20230215_9781803569604_373 9781803569604 9781803569598 9781803569611 https://directory.doabooks.org/handle/20.500.12854/97335 eng image/jpeg n/a https://www.intechopen.com/books/11903 https://mts.intechopen.com/storage/books/11903/authors_book/authors_book.pdf IntechOpen IntechOpen 10.5772/intechopen.102264 10.5772/intechopen.102264 78a36484-2c0c-47cb-ad67-2b9f5cd4a8f6 9781803569604 9781803569598 9781803569611 IntechOpen 122 open access |
| spellingShingle | Chemistry thema EDItEUR::P Mathematics and Science::PN Chemistry::PNN Organic chemistry Covalent Organic Frameworks |
| title | Covalent Organic Frameworks |
| title_full | Covalent Organic Frameworks |
| title_fullStr | Covalent Organic Frameworks |
| title_full_unstemmed | Covalent Organic Frameworks |
| title_short | Covalent Organic Frameworks |
| title_sort | covalent organic frameworks |
| topic | Chemistry thema EDItEUR::P Mathematics and Science::PN Chemistry::PNN Organic chemistry |
| topic_facet | Chemistry thema EDItEUR::P Mathematics and Science::PN Chemistry::PNN Organic chemistry |
| url | ONIX_20230215_9781803569604_373 |