Tetrel Bonds
The replacement of the bridging H atom in H-bonds by a multitude of other, more electronegative, atoms has led to the rapidly growing study of related noncovalent bonds generally known as halogen, chalcogen, and pnicogen bonds. It has recently been recognized that elements of the tetrel family (C, S...
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MDPI - Multidisciplinary Digital Publishing Institute
2023
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| Online dostop: | ONIX_20230405_9783036502366_180 |
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| description | The replacement of the bridging H atom in H-bonds by a multitude of other, more electronegative, atoms has led to the rapidly growing study of related noncovalent bonds generally known as halogen, chalcogen, and pnicogen bonds. It has recently been recognized that elements of the tetrel family (C, Si, Ge, Sn, Pb) also engage in such bonds, wherein the tetrel atom serves as an electron acceptor to an incoming Lewis base, and that these bonds can be quite strong. This type of bond has the potential to be of importance comparable even to that of the well-researched H-bond, as it may be far more prevalent than has been realized, perhaps a common feature of chemical and biological systems too numerous to mention. The articles included in this volume delve into the many facets of tetrel bonds: the factors determining their strength, their geometrical requirements, various phenomena in which they play an outsized role, and the means by which they can be detected and measured. |
| format | Online |
| id | doab-20.500.12854ir-98901 |
| institution | Directory of Open Access Books |
| language | eng |
| publishDate | 2023 |
| publishDateRange | 2023 |
| publishDateSort | 2023 |
| publisher | MDPI - Multidisciplinary Digital Publishing Institute |
| publisherStr | MDPI - Multidisciplinary Digital Publishing Institute |
| record_format | ojs |
| spelling | doab-20.500.12854ir-989012024-04-09T23:16:41Z Tetrel Bonds Scheiner, Steve noncovalent bond carbon bond   sigma-hole pi-hole methyl groups spectroscopy pnicogen bond chalcogen bond halogen bond anion binding thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TB Technology: general issues The replacement of the bridging H atom in H-bonds by a multitude of other, more electronegative, atoms has led to the rapidly growing study of related noncovalent bonds generally known as halogen, chalcogen, and pnicogen bonds. It has recently been recognized that elements of the tetrel family (C, Si, Ge, Sn, Pb) also engage in such bonds, wherein the tetrel atom serves as an electron acceptor to an incoming Lewis base, and that these bonds can be quite strong. This type of bond has the potential to be of importance comparable even to that of the well-researched H-bond, as it may be far more prevalent than has been realized, perhaps a common feature of chemical and biological systems too numerous to mention. The articles included in this volume delve into the many facets of tetrel bonds: the factors determining their strength, their geometrical requirements, various phenomena in which they play an outsized role, and the means by which they can be detected and measured. 2023-04-05T12:58:06Z 2023-04-05T12:58:06Z 2023 book ONIX_20230405_9783036502366_180 9783036502366 9783036502373 https://directory.doabooks.org/handle/20.500.12854/98901 eng application/octet-stream Attribution 4.0 International https://mdpi.com/books/pdfview/book/6954 https://mdpi.com/books/pdfview/book/6954 MDPI - Multidisciplinary Digital Publishing Institute 10.3390/books978-3-0365-0237-3 10.3390/books978-3-0365-0237-3 46cabcaa-dd94-4bfe-87b4-55023c1b36d0 9783036502366 9783036502373 252 Basel open access |
| spellingShingle | noncovalent bond carbon bond   sigma-hole pi-hole methyl groups spectroscopy pnicogen bond chalcogen bond halogen bond anion binding thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TB Technology: general issues Tetrel Bonds |
| title | Tetrel Bonds |
| title_full | Tetrel Bonds |
| title_fullStr | Tetrel Bonds |
| title_full_unstemmed | Tetrel Bonds |
| title_short | Tetrel Bonds |
| title_sort | tetrel bonds |
| topic | noncovalent bond carbon bond   sigma-hole pi-hole methyl groups spectroscopy pnicogen bond chalcogen bond halogen bond anion binding thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TB Technology: general issues |
| topic_facet | noncovalent bond carbon bond   sigma-hole pi-hole methyl groups spectroscopy pnicogen bond chalcogen bond halogen bond anion binding thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TB Technology: general issues |
| url | ONIX_20230405_9783036502366_180 |