Solid-Phase Microextraction and Related Techniques in Bioanalysis

Bioanalysis of endogenous substances, metabolites, and contaminants poisons is important in analyses of biological functions, metabolomics, forensic toxicology, patient diagnosis and biomonitoring of human exposure to hazardous chemicals. In these analyses, methods of sample preparation are essentia...

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collection Directory of Open Access Books
description Bioanalysis of endogenous substances, metabolites, and contaminants poisons is important in analyses of biological functions, metabolomics, forensic toxicology, patient diagnosis and biomonitoring of human exposure to hazardous chemicals. In these analyses, methods of sample preparation are essential for the isolation and concentration of target analytes from complex biological matrices. These processes, however, are time-consuming, labor-intensive and error-prone, and markedly influence the reliability and accuracy of determining target analytes. Thus, efficient sample preparation techniques and their integration with analytical methods have become significant. Solid-phase microextraction (SPME) is a simple and convenient sample preparation technique that has enabled automation, miniaturization, high-throughput performance, and online coupling with analytical instruments. Moreover, SPME has reduced analysis times, as well as solvent and disposal costs.This reprint consists of 14 original, peer-reviewed papers for the Special Issue in the MDPI journal Molecules. The topics covered include headspace fiber SPME (HS-SPME) gas chromatography-mass spectrometry (GC-MS), HS-in-needle microextraction GC-MS, thin film SPME liquid chromatography-tandem mass spectrometry (LC-MS/MS), magnetic solid phase extraction LC-MS/MS, in-tube SPME LC-MS/MS and in-tube SPME LC-UV. Samples analyzed include plant-derived volatile organic compounds; body odor; metabolites in urine, plasma and saliva sample; and biomarkers of tobacco smoke exposure in hair and environmental estrogens.
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publisherStr MDPI - Multidisciplinary Digital Publishing Institute
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spelling doab-20.500.12854ir-989252024-03-28T03:33:01Z Solid-Phase Microextraction and Related Techniques in Bioanalysis Kataoka, Hiroyuki tobacco-specific nitrosamines hair exposure biomarkers in-tube solid-phase microextraction (SPME) liquid chromatography-tandem mass spectrometry (LC–MS/MS) bioanalysis carbon materials HPLC–MS biological matrices solid-phase extraction sample preparation bladder cancer (BC) metabolomics solid phase microextraction (SPME) liquid chromatography mass spectrometry urine Myrtaceae native fruit volatile compounds sesquiterpenes body odor 2-nonenal wiping method pasting method solid-phase microextraction (HS–SPME) gas chromatography–mass spectrometry (GC–MS) passive smoking nicotine cotinine risk assessment headspace solid-phase microextraction Cerrado aroma volatile organic compounds Herpetospermum pedunculosum HS-SPME-GC-MS dioecious plant bud volatile compound multivariate statistical analysis green peach aphids VOCs parasitoids Aphidus colemani Aphelinus abdominalis cabbage cerrado Anacardiaceae aroeira biological properties virtual screening chemoinformatics volatile organic compounds (VOCs) headspace solid-phase microextraction (HS-SPME) SPME-GC-MS stored-product insect pests Tribolium castaneum Rhyzopertha dominica Sitophilus granarius titanium wire superhydrophobic superhydrophilic in-tube solid-phase microextraction high-performance liquid chromatography sulfated steroid metabolites saliva online automated analysis in-tube solid-phase microextraction (IT-SPME) liquid chromatography–tandem mass spectrometry (LC–MS/MS) stable isotope dilution human body odor GO:PANI/ZNRs/ZIF−8 response surface methodology needle-based adsorbent headspace-in needle microextraction n/a thema EDItEUR::G Reference, Information and Interdisciplinary subjects::GP Research and information: general thema EDItEUR::P Mathematics and Science::PN Chemistry thema EDItEUR::P Mathematics and Science::PN Chemistry::PNF Analytical chemistry Bioanalysis of endogenous substances, metabolites, and contaminants poisons is important in analyses of biological functions, metabolomics, forensic toxicology, patient diagnosis and biomonitoring of human exposure to hazardous chemicals. In these analyses, methods of sample preparation are essential for the isolation and concentration of target analytes from complex biological matrices. These processes, however, are time-consuming, labor-intensive and error-prone, and markedly influence the reliability and accuracy of determining target analytes. Thus, efficient sample preparation techniques and their integration with analytical methods have become significant. Solid-phase microextraction (SPME) is a simple and convenient sample preparation technique that has enabled automation, miniaturization, high-throughput performance, and online coupling with analytical instruments. Moreover, SPME has reduced analysis times, as well as solvent and disposal costs.This reprint consists of 14 original, peer-reviewed papers for the Special Issue in the MDPI journal Molecules. The topics covered include headspace fiber SPME (HS-SPME) gas chromatography-mass spectrometry (GC-MS), HS-in-needle microextraction GC-MS, thin film SPME liquid chromatography-tandem mass spectrometry (LC-MS/MS), magnetic solid phase extraction LC-MS/MS, in-tube SPME LC-MS/MS and in-tube SPME LC-UV. Samples analyzed include plant-derived volatile organic compounds; body odor; metabolites in urine, plasma and saliva sample; and biomarkers of tobacco smoke exposure in hair and environmental estrogens. 2023-04-05T12:59:21Z 2023-04-05T12:59:21Z 2023 book ONIX_20230405_9783036570471_204 9783036570471 9783036570464 https://directory.doabooks.org/handle/20.500.12854/98925 eng application/octet-stream Attribution 4.0 International https://mdpi.com/books/pdfview/book/6978 https://mdpi.com/books/pdfview/book/6978 MDPI - Multidisciplinary Digital Publishing Institute 10.3390/books978-3-0365-7046-4 10.3390/books978-3-0365-7046-4 46cabcaa-dd94-4bfe-87b4-55023c1b36d0 9783036570471 9783036570464 198 Basel open access
spellingShingle tobacco-specific nitrosamines
hair
exposure biomarkers
in-tube solid-phase microextraction (SPME)
liquid chromatography-tandem mass spectrometry (LC–MS/MS)
bioanalysis
carbon materials
HPLC–MS
biological matrices
solid-phase extraction
sample preparation
bladder cancer (BC)
metabolomics
solid phase microextraction (SPME)
liquid chromatography
mass spectrometry
urine
Myrtaceae
native fruit
volatile compounds
sesquiterpenes
body odor
2-nonenal
wiping method
pasting method
solid-phase microextraction (HS–SPME)
gas chromatography–mass spectrometry (GC–MS)
passive smoking
nicotine
cotinine
risk assessment
headspace solid-phase microextraction
Cerrado
aroma
volatile organic compounds
Herpetospermum pedunculosum
HS-SPME-GC-MS
dioecious plant
bud
volatile compound
multivariate statistical analysis
green peach aphids
VOCs
parasitoids
Aphidus colemani
Aphelinus abdominalis
cabbage
cerrado
Anacardiaceae
aroeira
biological properties
virtual screening
chemoinformatics
volatile organic compounds (VOCs)
headspace solid-phase microextraction (HS-SPME)
SPME-GC-MS
stored-product insect pests
Tribolium castaneum
Rhyzopertha dominica
Sitophilus granarius
titanium wire
superhydrophobic
superhydrophilic
in-tube solid-phase microextraction
high-performance liquid chromatography
sulfated steroid metabolites
saliva
online automated analysis
in-tube solid-phase microextraction (IT-SPME)
liquid chromatography–tandem mass spectrometry (LC–MS/MS)
stable isotope dilution
human body odor
GO:PANI/ZNRs/ZIF−8
response surface methodology
needle-based adsorbent
headspace-in needle microextraction
n/a
thema EDItEUR::G Reference, Information and Interdisciplinary subjects::GP Research and information: general
thema EDItEUR::P Mathematics and Science::PN Chemistry
thema EDItEUR::P Mathematics and Science::PN Chemistry::PNF Analytical chemistry
Solid-Phase Microextraction and Related Techniques in Bioanalysis
title Solid-Phase Microextraction and Related Techniques in Bioanalysis
title_full Solid-Phase Microextraction and Related Techniques in Bioanalysis
title_fullStr Solid-Phase Microextraction and Related Techniques in Bioanalysis
title_full_unstemmed Solid-Phase Microextraction and Related Techniques in Bioanalysis
title_short Solid-Phase Microextraction and Related Techniques in Bioanalysis
title_sort solid phase microextraction and related techniques in bioanalysis
topic tobacco-specific nitrosamines
hair
exposure biomarkers
in-tube solid-phase microextraction (SPME)
liquid chromatography-tandem mass spectrometry (LC–MS/MS)
bioanalysis
carbon materials
HPLC–MS
biological matrices
solid-phase extraction
sample preparation
bladder cancer (BC)
metabolomics
solid phase microextraction (SPME)
liquid chromatography
mass spectrometry
urine
Myrtaceae
native fruit
volatile compounds
sesquiterpenes
body odor
2-nonenal
wiping method
pasting method
solid-phase microextraction (HS–SPME)
gas chromatography–mass spectrometry (GC–MS)
passive smoking
nicotine
cotinine
risk assessment
headspace solid-phase microextraction
Cerrado
aroma
volatile organic compounds
Herpetospermum pedunculosum
HS-SPME-GC-MS
dioecious plant
bud
volatile compound
multivariate statistical analysis
green peach aphids
VOCs
parasitoids
Aphidus colemani
Aphelinus abdominalis
cabbage
cerrado
Anacardiaceae
aroeira
biological properties
virtual screening
chemoinformatics
volatile organic compounds (VOCs)
headspace solid-phase microextraction (HS-SPME)
SPME-GC-MS
stored-product insect pests
Tribolium castaneum
Rhyzopertha dominica
Sitophilus granarius
titanium wire
superhydrophobic
superhydrophilic
in-tube solid-phase microextraction
high-performance liquid chromatography
sulfated steroid metabolites
saliva
online automated analysis
in-tube solid-phase microextraction (IT-SPME)
liquid chromatography–tandem mass spectrometry (LC–MS/MS)
stable isotope dilution
human body odor
GO:PANI/ZNRs/ZIF−8
response surface methodology
needle-based adsorbent
headspace-in needle microextraction
n/a
thema EDItEUR::G Reference, Information and Interdisciplinary subjects::GP Research and information: general
thema EDItEUR::P Mathematics and Science::PN Chemistry
thema EDItEUR::P Mathematics and Science::PN Chemistry::PNF Analytical chemistry
topic_facet tobacco-specific nitrosamines
hair
exposure biomarkers
in-tube solid-phase microextraction (SPME)
liquid chromatography-tandem mass spectrometry (LC–MS/MS)
bioanalysis
carbon materials
HPLC–MS
biological matrices
solid-phase extraction
sample preparation
bladder cancer (BC)
metabolomics
solid phase microextraction (SPME)
liquid chromatography
mass spectrometry
urine
Myrtaceae
native fruit
volatile compounds
sesquiterpenes
body odor
2-nonenal
wiping method
pasting method
solid-phase microextraction (HS–SPME)
gas chromatography–mass spectrometry (GC–MS)
passive smoking
nicotine
cotinine
risk assessment
headspace solid-phase microextraction
Cerrado
aroma
volatile organic compounds
Herpetospermum pedunculosum
HS-SPME-GC-MS
dioecious plant
bud
volatile compound
multivariate statistical analysis
green peach aphids
VOCs
parasitoids
Aphidus colemani
Aphelinus abdominalis
cabbage
cerrado
Anacardiaceae
aroeira
biological properties
virtual screening
chemoinformatics
volatile organic compounds (VOCs)
headspace solid-phase microextraction (HS-SPME)
SPME-GC-MS
stored-product insect pests
Tribolium castaneum
Rhyzopertha dominica
Sitophilus granarius
titanium wire
superhydrophobic
superhydrophilic
in-tube solid-phase microextraction
high-performance liquid chromatography
sulfated steroid metabolites
saliva
online automated analysis
in-tube solid-phase microextraction (IT-SPME)
liquid chromatography–tandem mass spectrometry (LC–MS/MS)
stable isotope dilution
human body odor
GO:PANI/ZNRs/ZIF−8
response surface methodology
needle-based adsorbent
headspace-in needle microextraction
n/a
thema EDItEUR::G Reference, Information and Interdisciplinary subjects::GP Research and information: general
thema EDItEUR::P Mathematics and Science::PN Chemistry
thema EDItEUR::P Mathematics and Science::PN Chemistry::PNF Analytical chemistry
url ONIX_20230405_9783036570471_204