Coordination Chemistry of Silicon
The chemistry of silicon has always been a field of major concern due to its proximity to carbon on the periodic table. From the molecular chemist's viewpoint, one of the most interesting differences between carbon and silicon is their divergent coordination behavior. In fact, silicon is prone to fo...
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| Formato: | Online |
| Idioma: | inglês |
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MDPI - Multidisciplinary Digital Publishing Institute
2021
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| Acesso em linha: | 32463 |
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| _version_ | 1869530407873019904 |
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| author | Inoue, Shigeyoshi |
| author_browse | Inoue, Shigeyoshi |
| author_facet | Inoue, Shigeyoshi |
| author_sort | Inoue, Shigeyoshi |
| collection | Directory of Open Access Books |
| description | The chemistry of silicon has always been a field of major concern due to its proximity to carbon on the periodic table. From the molecular chemist's viewpoint, one of the most interesting differences between carbon and silicon is their divergent coordination behavior. In fact, silicon is prone to form hyper-coordinate organosilicon complexes, and, as conveyed by reports in the literature, highly sophisticated ligand systems are required to furnish low-coordinate organosilicon complexes. Tremendous progress in experimental, as well as computational, techniques has granted synthetic access to a broad range of coordination numbers for silicon, and the scientific endeavor, which was ongoing for decades, was rewarded with landmark discoveries in the field of organosilicon chemistry. Molecular congeners of silicon(0), as well as silicon oxides, were unveiled, and the prominent group 14 metalloid proved its applicability in homogenous catalysis as a supportive ligand or even as a center of catalytic activity. This book focuses on the most recent advances in the coordination chemistry of silicon with transition metals as well as main group elements, including the stabilization of low-valent silicon species through the coordination of electron donor ligands. Therefore, this book is associated with the development of novel synthetic methodologies, structural elucidations, bonding analysis, and also possible applications in catalysis or chemical transformations using related organosilicon compounds. |
| format | Online |
| id | doab-20.500.12854ir-44062 |
| institution | Directory of Open Access Books |
| language | eng |
| publishDate | 2021 |
| publishDateRange | 2021 |
| publishDateSort | 2021 |
| publisher | MDPI - Multidisciplinary Digital Publishing Institute |
| publisherStr | MDPI - Multidisciplinary Digital Publishing Institute |
| record_format | ojs |
| spelling | doab-20.500.12854ir-440622024-04-05T12:39:52Z Coordination Chemistry of Silicon Inoue, Shigeyoshi QD1-999 QD146-197 Q1-390 cluster molecular orbital analysis bond activation X-ray diffraction silsesquioxanes digermacyclobutadiene intermetallic bond germanium computational chemistry ?-electron systems isocyanide X-ray crystallography cyclic organopolysilane disilene ruthenium platinum DFT Photostability silicon surfaces stereochemistry palladium distorted coordination <sup>29</sup>Si NMR spectroscopy organosilicon disilanylene polymer Si–Cl activation adsorption AIM siliconoid nanoparticle disiloxane tetrols germylene hydrogen bonding TiO<sub>2</sub> dehydrogenative alkoxylation siloxanes 2-silylpyrrolidines bonding analysis ?-chloro-?-hydrooligosilane hydrido complex oxidative addition photoreaction template surface modification titanium bromosilylenes host-guest chemistry hydrogen bonds salt-free <i>N</i>-heterocyclic carbines silicon cluster condensation silyliumylidenes Baird’s rule <i>N</i>-heterocyclic carbenes reductant main group coordination chemistry molecular cage subvalent compounds isomerization silanetriols germathioacid chloride dehydrobromination <i>N</i>-heterocyclic carbene mechanistic insights ligand-exchange reaction bridging silylene ligand dye-sensitized solar cell silylene computation functionalization silicon digermene <i>N</i>-Heterocyclic tetrylene density functional theory primary silane small molecule activation excited state aromaticity germanethione supramolecular chemistry thema EDItEUR::P Mathematics and Science::PN Chemistry The chemistry of silicon has always been a field of major concern due to its proximity to carbon on the periodic table. From the molecular chemist's viewpoint, one of the most interesting differences between carbon and silicon is their divergent coordination behavior. In fact, silicon is prone to form hyper-coordinate organosilicon complexes, and, as conveyed by reports in the literature, highly sophisticated ligand systems are required to furnish low-coordinate organosilicon complexes. Tremendous progress in experimental, as well as computational, techniques has granted synthetic access to a broad range of coordination numbers for silicon, and the scientific endeavor, which was ongoing for decades, was rewarded with landmark discoveries in the field of organosilicon chemistry. Molecular congeners of silicon(0), as well as silicon oxides, were unveiled, and the prominent group 14 metalloid proved its applicability in homogenous catalysis as a supportive ligand or even as a center of catalytic activity. This book focuses on the most recent advances in the coordination chemistry of silicon with transition metals as well as main group elements, including the stabilization of low-valent silicon species through the coordination of electron donor ligands. Therefore, this book is associated with the development of novel synthetic methodologies, structural elucidations, bonding analysis, and also possible applications in catalysis or chemical transformations using related organosilicon compounds. 2021-02-11T10:36:03Z 2021-02-11T10:36:03Z 2019-03-08 11:42:05 2019 book 32463 9783038976387 https://directory.doabooks.org/handle/20.500.12854/44062 eng image/jpeg Attribution-NonCommercial-NoDerivatives 4.0 International https://mdpi.com/books/pdfview/book/1156 MDPI - Multidisciplinary Digital Publishing Institute 10.3390/books978-3-03897-639-4 10.3390/books978-3-03897-639-4 46cabcaa-dd94-4bfe-87b4-55023c1b36d0 9783038976387 225 open access |
| spellingShingle | QD1-999 QD146-197 Q1-390 cluster molecular orbital analysis bond activation X-ray diffraction silsesquioxanes digermacyclobutadiene intermetallic bond germanium computational chemistry ?-electron systems isocyanide X-ray crystallography cyclic organopolysilane disilene ruthenium platinum DFT Photostability silicon surfaces stereochemistry palladium distorted coordination <sup>29</sup>Si NMR spectroscopy organosilicon disilanylene polymer Si–Cl activation adsorption AIM siliconoid nanoparticle disiloxane tetrols germylene hydrogen bonding TiO<sub>2</sub> dehydrogenative alkoxylation siloxanes 2-silylpyrrolidines bonding analysis ?-chloro-?-hydrooligosilane hydrido complex oxidative addition photoreaction template surface modification titanium bromosilylenes host-guest chemistry hydrogen bonds salt-free <i>N</i>-heterocyclic carbines silicon cluster condensation silyliumylidenes Baird’s rule <i>N</i>-heterocyclic carbenes reductant main group coordination chemistry molecular cage subvalent compounds isomerization silanetriols germathioacid chloride dehydrobromination <i>N</i>-heterocyclic carbene mechanistic insights ligand-exchange reaction bridging silylene ligand dye-sensitized solar cell silylene computation functionalization silicon digermene <i>N</i>-Heterocyclic tetrylene density functional theory primary silane small molecule activation excited state aromaticity germanethione supramolecular chemistry thema EDItEUR::P Mathematics and Science::PN Chemistry Inoue, Shigeyoshi Coordination Chemistry of Silicon |
| title | Coordination Chemistry of Silicon |
| title_full | Coordination Chemistry of Silicon |
| title_fullStr | Coordination Chemistry of Silicon |
| title_full_unstemmed | Coordination Chemistry of Silicon |
| title_short | Coordination Chemistry of Silicon |
| title_sort | coordination chemistry of silicon |
| topic | QD1-999 QD146-197 Q1-390 cluster molecular orbital analysis bond activation X-ray diffraction silsesquioxanes digermacyclobutadiene intermetallic bond germanium computational chemistry ?-electron systems isocyanide X-ray crystallography cyclic organopolysilane disilene ruthenium platinum DFT Photostability silicon surfaces stereochemistry palladium distorted coordination <sup>29</sup>Si NMR spectroscopy organosilicon disilanylene polymer Si–Cl activation adsorption AIM siliconoid nanoparticle disiloxane tetrols germylene hydrogen bonding TiO<sub>2</sub> dehydrogenative alkoxylation siloxanes 2-silylpyrrolidines bonding analysis ?-chloro-?-hydrooligosilane hydrido complex oxidative addition photoreaction template surface modification titanium bromosilylenes host-guest chemistry hydrogen bonds salt-free <i>N</i>-heterocyclic carbines silicon cluster condensation silyliumylidenes Baird’s rule <i>N</i>-heterocyclic carbenes reductant main group coordination chemistry molecular cage subvalent compounds isomerization silanetriols germathioacid chloride dehydrobromination <i>N</i>-heterocyclic carbene mechanistic insights ligand-exchange reaction bridging silylene ligand dye-sensitized solar cell silylene computation functionalization silicon digermene <i>N</i>-Heterocyclic tetrylene density functional theory primary silane small molecule activation excited state aromaticity germanethione supramolecular chemistry thema EDItEUR::P Mathematics and Science::PN Chemistry |
| topic_facet | QD1-999 QD146-197 Q1-390 cluster molecular orbital analysis bond activation X-ray diffraction silsesquioxanes digermacyclobutadiene intermetallic bond germanium computational chemistry ?-electron systems isocyanide X-ray crystallography cyclic organopolysilane disilene ruthenium platinum DFT Photostability silicon surfaces stereochemistry palladium distorted coordination <sup>29</sup>Si NMR spectroscopy organosilicon disilanylene polymer Si–Cl activation adsorption AIM siliconoid nanoparticle disiloxane tetrols germylene hydrogen bonding TiO<sub>2</sub> dehydrogenative alkoxylation siloxanes 2-silylpyrrolidines bonding analysis ?-chloro-?-hydrooligosilane hydrido complex oxidative addition photoreaction template surface modification titanium bromosilylenes host-guest chemistry hydrogen bonds salt-free <i>N</i>-heterocyclic carbines silicon cluster condensation silyliumylidenes Baird’s rule <i>N</i>-heterocyclic carbenes reductant main group coordination chemistry molecular cage subvalent compounds isomerization silanetriols germathioacid chloride dehydrobromination <i>N</i>-heterocyclic carbene mechanistic insights ligand-exchange reaction bridging silylene ligand dye-sensitized solar cell silylene computation functionalization silicon digermene <i>N</i>-Heterocyclic tetrylene density functional theory primary silane small molecule activation excited state aromaticity germanethione supramolecular chemistry thema EDItEUR::P Mathematics and Science::PN Chemistry |
| url | 32463 |
| work_keys_str_mv | AT inoueshigeyoshi coordinationchemistryofsilicon |