Coordination Chemistry of Silicon

The chemistry of silicon has always been a field of major concern due to its proximity to carbon on the periodic table. From the molecular chemist's viewpoint, one of the most interesting differences between carbon and silicon is their divergent coordination behavior. In fact, silicon is prone to fo...

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Bibliographische Detailangaben
1. Verfasser:	Inoue, Shigeyoshi
Format:	Online
Sprache:	Englisch
Veröffentlicht:	MDPI - Multidisciplinary Digital Publishing Institute 2021
Schlagworte:	QD1-999 QD146-197 Q1-390 cluster molecular orbital analysis bond activation X-ray diffraction silsesquioxanes digermacyclobutadiene intermetallic bond germanium computational chemistry ?-electron systems isocyanide X-ray crystallography cyclic organopolysilane disilene ruthenium platinum DFT Photostability silicon surfaces stereochemistry palladium distorted coordination <sup>29</sup>Si NMR spectroscopy organosilicon disilanylene polymer Si–Cl activation adsorption AIM siliconoid nanoparticle disiloxane tetrols germylene hydrogen bonding TiO<sub>2</sub> dehydrogenative alkoxylation siloxanes 2-silylpyrrolidines bonding analysis ?-chloro-?-hydrooligosilane hydrido complex oxidative addition photoreaction template surface modification titanium bromosilylenes host-guest chemistry hydrogen bonds salt-free <i>N</i>-heterocyclic carbines silicon cluster condensation silyliumylidenes Baird’s rule <i>N</i>-heterocyclic carbenes reductant main group coordination chemistry molecular cage subvalent compounds isomerization silanetriols germathioacid chloride dehydrobromination <i>N</i>-heterocyclic carbene mechanistic insights ligand-exchange reaction bridging silylene ligand dye-sensitized solar cell silylene computation functionalization silicon digermene <i>N</i>-Heterocyclic tetrylene density functional theory primary silane small molecule activation excited state aromaticity germanethione supramolecular chemistry thema EDItEUR::P Mathematics and Science::PN Chemistry
Online-Zugang:	32463
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Coordination Chemistry of Silicon

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